Three-Dimensional Metal(II)-Organic Coordination Polymers from Binuclear, Trinuclear, and Polynuclear Clusters Bridged by p-Benzenediacrylates: Syntheses, Topologies, Photosensitive Properties, and Hydrogen Uptake

被引：47

作者：

Huang, Kun-Lin ^{[1
]}

Liu, Xi ^{[1
]}

Li, Ji-Kun ^{[2
]}

Ding, Yan-Wei ^{[3
]}

Chen, Xin ^{[1
]}

Zhang, Ming-Xing ^{[1
]}

Xu, Xiao-Bo ^{[1
]}

Song, Xiao-Jun ^{[1
]}

机构：

[1] Chongqing Normal Univ, Coll Chem, Chongqing 400047, Peoples R China

[2] Taishan Univ, Dept Mat & Chem Engn, Tai An 271021, Shandong, Peoples R China

[3] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 04期

关键词：

METAL-ORGANIC FRAMEWORKS; RETICULAR CHEMISTRY; CRYSTAL-STRUCTURE; CARBOXYLATE FRAMEWORKS; SUPRAMOLECULAR NETWORK; HYDROTHERMAL SYNTHESIS; 3-PERIODIC NETS; DESIGN; TETRACARBOXYLATE; SORPTION;

D O I：

10.1021/cg900579s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal/solvothermal reactions of metal(II) nitrate hydrates with organic ligands (p-benzenediacrylic acid = H(2)pbda, 1,10-phenanthroline = phen) generate three three-dimensional (3-D) coordination polymers with (3,4)connected (4.8.10)(4(2).6.8 x 10(2)) topology (1, {[Cd-2(pbda)(2)(phen)(2)](H2O)}(n)), 2-fold interpenetrating CdSO4-type open framework (2, [Zn-3(pbda)(3)(phen)(2)](n)), and 3-fold interpenetrated sra net (3, [Pb(pbda)](n)). The porous zinc open framework 2 has the typical type-1 sorption curve with a H-2 uptake of 31 cm(3).g(-1)(STP) at 77 K, BET surface area of 65.84 m(2).g(-1), and meso-[Zn-2(pbda)(2)] helical motifs. With strong luminescent emission at 504 nm, complex 2 may be suitable as an excellent candidate for solid-state photosensitive materials at room temperature.

引用

页码：1508 / 1515

页数：8

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