Kinetics and Mechanism of The Oxidation of 2-Methylindole by Alkaline Potassium Hexacyanoferrate(III)

被引：0

作者：

Iqab, A. ^{[1
]}

机构：

[1] Arab Amer Univ, Dept Chem, Jenin, Palestine

来源：

EGYPTIAN JOURNAL OF CHEMISTRY | 2021年 / 64卷 / 03期

关键词：

2-methylindole; hexacyanoferrate(III); 2-methylindolin-3-one; kinetics and oxidation; INDOLE;

D O I：

10.21608/EJCHEM.2020.22459.2338

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 2-methylindole with hexacyanoferrate(III) in alkaline media to produce the corresponding 2-methylindolin-3one has been studied at constant temperature and ionic strength. The reaction followed first order kinetics with respect to [2methylindole], [OH-] and [Fe(CN)63-]. The effects of added electrolytes, potassium hexacyanoferrate(II), relative permitivity and temperature have also been studied. On the basis of experimental observations, a probable reaction mechanism has been proposed.

引用

页码：1441 / 1446

页数：6

共 21 条

[1] KINETICS AND MECHANISM OF OS(VIII)-CATALYZED HEXACYANOFERRATE(III) OXIDATION OF ALPHA-AMINO-ACIDS IN ALKALINE-MEDIUM
ACHARYA, RC
SARAN, NK
RAO, SR
DAS, MN
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (02) : 143 - 151
[2] AL-Subu M. M., 2001, AN NAJAH U J RES, V15, P29
[3] Osmium(VIII)-catalyzed oxidation of pentamethylene sulfide
Al-Subu, MM
[J]. TRANSITION METAL CHEMISTRY, 2004, 29 (01) : 91 - 95
[4] AlBonayan A., SCI J CHEM, V4
[5] Amir M, 1997, INDIAN J CHEM B, V36, P96
[6] KINETICS OF OXIDATION OF BUTANE 2,3-DIOL BY OSMIUM(VIII)
ANAND, BH
MENGHANI, GD
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1980, 12 (04) : 225 - 230
[7] Oxidation of indole-3-acetic acid by peroxomonosulphate: A kinetic and mechanistic study
Chandramohan, G
Kalyanasundharam, S
Renganathan, R
[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2002, 34 (10) : 569 - 574
[8] Devra Vijay, 2012, RASAYAN J CHEM, V5, P67
[9] Kinetic, mechanistic and spectral studies for the oxidation of sulfanilic acid by alkaline hexacyanoferrate(III)
Farokhi, SA
Nandibewoor, ST
[J]. TETRAHEDRON, 2003, 59 (38) : 7595 - 7602
[10] Hannoun M., 2003, CHEM HETEROCYCL COM+, V39, P559

← 1 2 3 →