A convenient one-pot synthesis of cyclam-β-cyclodextrins new ligands

被引：19
|
作者：
Charbonnier, F [1 ]
Humbert, T [1 ]
Marsura, A [1 ]
机构：
[1] Univ Nancy 1, Fac Sci Pharmaceut & Biol, CNRS, Unite Mixte Rech, F-54001 Nancy, France
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 21期
关键词：
beta-cyclodextrin; polyazamacrocycles; Eu (III) complex;
D O I：
10.1016/S0040-4039(98)00598-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The present work describes the one-pot synthesis of new polyazamacrocyclic compounds 4-7 having hydrophobic hosts cavities (beta-cyclodextrins) attached to a metal chelating aza-macrocycle by ureido spacer arms. A coupling average of 30% was obtained, proving the efficiency of the "phosphinimine" method for a rapid access to new supramolecular devices. The subsequent complexation of 6 with EuCl3 give the stable complex 8. Preliminary results on fluorescence properties are reported. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：3481 / 3484
页数：4
相关论文
共 50 条
  • [1] A Convenient One-Pot Synthesis of Cyclam- QQ -Cyclodextrins New Ligands
    Charbonnier, F.
    Humbert, T.
    Marsura, A.
    Tetrahedron Letters, 39 (21):
  • [2] A CONVENIENT ONE-POT SYNTHESIS OF ACYCLONUCLEOSIDES
    UBASAWA, M
    TAKASHIMA, H
    SEKIYA, K
    CHEMICAL & PHARMACEUTICAL BULLETIN, 1995, 43 (01) : 142 - 143
  • [3] A convenient one-pot synthesis of stannylsilanes
    Hummeltenberg, R
    Jurkschat, K
    Uhlig, F
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 123 : 255 - 261
  • [4] One-pot synthesis of β-diketimine ligands
    El-Zoghbi, Ibrahim
    Ased, Aysha
    Oguadinma, Paul O.
    Tchirioua, Ekou
    Schaper, Frank
    CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 2010, 88 (10): : 1040 - 1045
  • [5] CONVENIENT ONE-POT SYNTHESIS OF SYMMETRICAL XANTHENES
    NOVAK, L
    KOVACS, P
    PIROK, G
    KOLONITS, P
    SZABO, E
    FEKETE, J
    WEISZFEILER, V
    SZANTAY, C
    SYNTHESIS-STUTTGART, 1995, (06): : 693 - 698
  • [6] A convenient one-pot synthesis of ethylene blue
    Cody, Jeremy A.
    Larrabee, Christian S.
    Clark, Michael D.
    Hlynchuk, Sofiya
    Tatum, Jacob A.
    TETRAHEDRON LETTERS, 2012, 53 (36) : 4896 - 4899
  • [7] Efficient and convenient one-pot synthesis of dioxadiazaphophepines
    Singh, MS
    Singh, AK
    SYNTHETIC COMMUNICATIONS, 2000, 30 (01) : 53 - 61
  • [8] Convenient, efficient one-pot synthesis of ferrocenylcyanide
    Zhang, JL
    Dong, CE
    Zhi, YG
    Zhang, LF
    CHINESE CHEMICAL LETTERS, 2000, 11 (02) : 107 - 108
  • [9] A CONVENIENT ONE-POT SYNTHESIS OF KETENE DITHIOACETALS
    VILLEMIN, D
    BENALLOUM, A
    SYNTHESIS-STUTTGART, 1991, (04): : 301 - 303
  • [10] Convenient one-pot synthesis of primary α-alkoxystannanes
    Kaufman, TS
    SYNLETT, 1997, (12) : 1377 - 1378
12345