Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln7(μ3-OH)8]13+ Cluster

被引：0
|
作者：
Liu, Lianchao [1 ]
Shen, Chaojun [1 ,2 ]
Dong, Fangfang [1 ]
Wang, Wenjing [2 ]
Yuan, Daqiang [2 ]
机构：
[1] Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2016年 / 34卷 / 02期
基金：
中国国家自然科学基金;
关键词：
MOFs; heptanuclear lanthanide cluster; magnetic; fluorescent; SINGLE-MOLECULE-MAGNET; CUBANE; LUMINESCENCE; COMPLEXES; DESIGN; TRANSITION; TB; GD;
D O I：
10.1002/cjoc.201500605
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two isostructural metal-organic frameworks formulated as [Gd-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(6)(H2O)]center dot DMF center dot H2O (1) and [Tb-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(5)(H2O)]center dot DMF center dot H2O (2) (H3L=3,5-di(4'-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln(7)(mu(3)-OH)(8)](13+) (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied.
引用
收藏
页码：210 / 214
页数：5
相关论文
共 27 条
  • [21] pH-dependent two novel 3D polynuclear cobalt(II) cluster-based metal-organic frameworks constructed from a tri-pyridyl-bis-amide and a polycarboxylate: assembly, structures and properties
    Wang, Xiuli
    Huang, Jingjing
    Liu, Lianli
    Liu, Guocheng
    Lin, Hongyan
    Zhang, Juwen
    Chen, Naili
    Qu, Yun
    RSC ADVANCES, 2013, 3 (33): : 13944 - 13952
  • [22] Two isostructural 3D metal-organic frameworks constructed from 1D [H2Mo4O14]n2n- chains and the flexible bis-pyridyl-bis-amide ligand
    Lin, Hongyan
    Xu, Chuang
    Wang, Xiuli
    Chang, Zhihan
    Tian, Aixiang
    Liu, Guocheng
    Zhang, Juwen
    INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 36 : 81 - 85
  • [23] A novel polyoxometalate-based metal-organic compound constructed from an unprecedented [Ag8(Hpyttz)4(H2pyttz)2] cluster and an in-situ [VW12O40]3- anion
    Wang, Xiuli
    Chen, Lufei
    Liu, Guocheng
    Luan, Jian
    Cao, Jingjing
    Gong, Chunhua
    Chang, Zhihan
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 53 : 64 - 67
  • [24] Two Metal-Organic Frameworks Based on Hexanuclear Cobalt-Hydroxyl Clusters or a Manganese-Hydroxyl Chain from Triangular [MII3(μ3-OH)] (M = Co and Mn) Units: Antiferromagnetic and Spin-Canting Antiferromagnetic Ordering with Soft-Magnetic Behavior
    Zhou, Lei
    Zhao, Manzhu
    Zhang, Xiaoying
    Zhang, Jingping
    INORGANIC CHEMISTRY, 2020, 59 (17) : 12017 - 12024
  • [25] Highly Selective Separation of C3H8 and C2H2 from CH4 within Two Water-Stable Zn5 Cluster-Based Metal-Organic Frameworks
    Kan, Liang
    Li, Guanghua
    Liu, Yunling
    ACS APPLIED MATERIALS & INTERFACES, 2020, 12 (16) : 18642 - 18649
  • [26] Two three-dimensional metal-organic frameworks from secondary building units of Zn8(OH)4(O2C-)12 and Zn2((OH)(O2C-)3:[Zn2(OH)(btc)]2(4,4′-bipy) and Zn2(OH)(btc)(pipe)
    Shi, Z
    Li, GH
    Wang, L
    Gao, L
    Chen, XB
    Hua, J
    Feng, SH
    CRYSTAL GROWTH & DESIGN, 2004, 4 (01) : 25 - 27
  • [27] Synthesis and Structural Characterization of Lanthanide-Containing Polytungsto-antimonate [{Sb3(μ3-O)2Ln(H2O)Ln(H2O)2}2(SbW10O37)2(SbW8O31)2]22-Molecules Deriving from the Decomposition of the [Sb8W36O132]24-Macroanion
    Dufaye, Maxime
    Duval, Sylvain
    Stoclet, Gregory
    Mara, Dimitrije
    Van Deun, Rik
    Loiseau, Thierry
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2020, 2020 (40) : 3837 - 3845
123