Synthesis and Characterization of Two Isostructural Lanthanide-Containing Metal-Organic Frameworks Constructed from an Unprecedented [Ln7(μ3-OH)8]13+ Cluster

被引：0
|
作者：
Liu, Lianchao [1 ]
Shen, Chaojun [1 ,2 ]
Dong, Fangfang [1 ]
Wang, Wenjing [2 ]
Yuan, Daqiang [2 ]
机构：
[1] Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2016年 / 34卷 / 02期
基金：
中国国家自然科学基金;
关键词：
MOFs; heptanuclear lanthanide cluster; magnetic; fluorescent; SINGLE-MOLECULE-MAGNET; CUBANE; LUMINESCENCE; COMPLEXES; DESIGN; TRANSITION; TB; GD;
D O I：
10.1002/cjoc.201500605
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two isostructural metal-organic frameworks formulated as [Gd-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(6)(H2O)]center dot DMF center dot H2O (1) and [Tb-7(L)(4)(mu(3)-OH)(8)(HCOO)(DMF)(5)(H2O)]center dot DMF center dot H2O (2) (H3L=3,5-di(4'-carboxylphenyl)benzoic acid) have been synthesized and structurally characterized. The building blocks of the structures are the heptanuclear lanthanide clusters of the dicubane-like type [Ln(7)(mu(3)-OH)(8)](13+) (Ln=Gd, Tb) which are formally assembled into porous three-dimensional networks through the linkage of L. Variable temperature magnetic studies down to 2 K reveal antiferromagnetic interactions in complex 1. Furthermore, the fluorescence property of 2 was also studied.
引用
收藏
页码：210 / 214
页数：5
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