Chemiresistive metal-stabilized thiyl radical films as highly selective ethylene sensors

被引:16
作者
Chauhan, Rajat [1 ]
Moreno, Monica [1 ]
Banda, Douglas M. [1 ]
Zamborini, Francis P. [1 ]
Grapperhaus, Craig A. [1 ]
机构
[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA
关键词
Ethylene;
D O I
10.1039/c4ra07560a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A highly selective chemiresistive ethylene sensor based on reversible and selective ligand-centered substrate binding to a metal-stabilized thiyl radical has been developed. The solid-state device efficiently differentiates between ethylene and other alkene analytes. The sensor is prepared by simple dropcast deposition of the complex as a film across a microgap gold electrode.
引用
收藏
页码:46787 / 46790
页数:4
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