High-resolution In situ analysis of nitrate and phosphate in the oligotrophic ocean

被引:50
作者
Adornato, Lori R.
Kaltenbacher, Eric A.
Greenhow, Danielle R.
Byrne, Robert H.
机构
[1] Univ S Florida, Coll Marine Sci, St Petersburg, FL 33701 USA
[2] SRI Int, St Petersburg, FL 33701 USA
关键词
D O I
10.1021/es0700855
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Accurate, high-resolution profiles of nitrate and phosphate distributions in the open ocean are difficult to obtain using conventional techniques. Concentrations typically range from low nanomolar levels in the stratified euphotic zone to micromolar levels below the nutricline. With multiple pumps, a heating cartridge, a long-path-length cell, and a multiwavelength spectrometer, the reconfigured Spectrophotometric Elemental Analysis System (SEAS) provides the capability to fully ascertain the distributions of nitrate and phosphate in the upper 200 m of the oligotrophic ocean. By utilizing a 15 cm path length and multiple wavelength spectrophotometry, SEAS can detect nitrate concentrations from 2 nM to 20 mu M and, with a 50 cm path length, can accurately measure phosphate concentrations from 1 nM to 1 mu M. SEAS is capable of collecting auxiliary data from up to four separate instruments, including a CTD, a fluorometer, a PAR sensor, and a second SEAS instrument. Sampling frequency depends on peripheral instrument selection and ranges from 0.4 to 0.75 Hz.
引用
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页码:4045 / 4052
页数:8
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