Synthesis, characterization and properties of novel poly(ester-amide-urethane)s

被引:4
作者
Mehdipour-Ataei, S [1 ]
Einollahy, P [1 ]
机构
[1] Iran Polymer & Petrochem Inst, Tehran, Iran
关键词
addition polymerization; copolymerization; polyurethanes; synthesis; thermal properties;
D O I
10.1002/masy.200451025
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
A diacid (TOBA) containing an ester group was synthesized by reaction of terephthaloyl chloride with 4-hydroxybenzoic acid. Reaction of the obtained diacid with thionyl chloride resulted in preparation of the related diacid chloride (TOBC). Nucleophilic substitution reaction of 4-aminophenol and also 5-amino-1-naphthol with the prepared diacid chloride afforded two aromatic diols containing ester and amide groups, respectively. Aromatic and semi-aromatic poly(ester-amide-urethane)s were prepared via addition polymerization of different diisocyanates with novel diols. The prepared polyurethanes showed improved thermal stability.
引用
收藏
页码:339 / 349
页数:11
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