Palladium-catalyzed C-O bond formation: direct synthesis of phenols and aryl/alkyl ethers from activated aryl halides

被引：99
|
作者：
Chen, Guoshu
Chan, Albert S. C.
Kwong, Fuk Yee
机构：
[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510402, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Open Lab Chirotechnol, Inst Mol Technol Drug Discovery & Synth, Kowloon, Hong Kong, Peoples R China
来源：
TETRAHEDRON LETTERS | 2007年 / 48卷 / 03期
关键词：
D O I：
10.1016/j.tetlet.2006.11.036
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple and efficient palladium-catalyzed carbon-oxygen bond formation is reported. The palladium-tri-tert-butylphosphine complex was found to be effective in converting haloarenes to corresponding substituted phenols. This methodology offers a direct transformation of aryl halides to phenols, as well as the straightforward application to generate a wide variety of diaryl or alkyl/aryl ethers. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码：473 / 476
页数：4
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