Theoretical studies of conformational analysis and intramolecular dynamic phenomena

被引：1

作者：

Alkorta, Ibon ^{[1
]}

Elguero, Jose ^{[1
]}

机构：

[1] CSIC, Inst Quim Med, Juan Cierva 3, E-28006 Madrid, Spain

来源：

STRUCTURAL CHEMISTRY | 2019年 / 30卷 / 06期

关键词：

Atranes; Atropisomerism; Carbohydrates; Chirality; Helicenes; Propellers; Scorpionates; X-RAY CRYSTALLOGRAPHY; CAMBRIDGE STRUCTURAL DATABASE; ABSOLUTE ASYMMETRIC-SYNTHESIS; KARPLUS-TYPE RELATIONSHIPS; SCALAR COUPLING-CONSTANTS; OPTICAL-ROTATORY POWER; SOLID-STATE; ROTATIONAL BARRIERS; ENANTIOSELECTIVE REACTIONS; SUPRAMOLECULAR CHEMISTRY;

D O I：

10.1007/s11224-019-01370-5

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This review reports our computational studies of a variety of topics related to conformational analyses and intramolecular dynamic phenomena. Single and double bonds, open and ring systems, and chiral molecules devoid of chiral centers (atropisomers, propellers, scorpionates, helicenes, truxenes) will be reported. Studies that followed our contributions and that are related to them will also be cited. Some curious aspects such as the absence of influence of static fields on absolute chirality, the extension of CIP rules to supramolecular systems, libration of phenyl groups, and the barrier of 1,16-dehydro[6]helicene will be discussed.

引用

页码：2029 / 2055

页数：27

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