Adsorption of nitrosamines in acidic solution by zeolites

被引：50

作者：

Zhou, CF ^{[1
]}

Zhu, JH ^{[1
]}

机构：

[1] Nanjing Univ, Dept Chem, Nanjing 210093, Peoples R China

来源：

CHEMOSPHERE | 2005年 / 58卷 / 01期

基金：

中国国家自然科学基金;

关键词：

N-nitrosopyrrolidine; acidic solution; adsorption; zeolite; anti-cancer;

D O I：

10.1016/j.chemosphere.2004.08.056

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Adsorption of N-nitrosopyrrolidine (NPYR) by zeolite NaZSM-5, Hbeta and NaZSM-11 in acidic solution with pH of 1 was investigated. The NPYR uptake process obeyed the first-rate Lagegren kinetic equation describing adsorption, and the equilibrium data were fitted to the Langmuir or Freundlich adsorption equation. Zeolite ZSM-5, Hbeta and NaZSM-11 possessed a higher adsorption capacity than amorphous silica or ordered mesoporous siliceous SBA-15, implying their potential application for adsorption of nitrosamines in gastric juice to anti-cancer. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：109 / 114

页数：6

共 20 条

[1]

CAMBLOR A, 1996, CHEM COMMUN, P2265

[2] DETAILED INVESTIGATION OF THE LATTICE STRUCTURE OF ZEOLITE ZSM-11 BY A COMBINATION OF SOLID-STATE NMR AND SYNCHROTRON X-RAY-DIFFRACTION TECHNIQUES [J].

FYFE, CA ;

GIES, H ;

KOKOTAILO, GT ;

PASZTOR, C ;

STROBL, H ;

COX, DE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (07) :2470-2474

[3] Release of nitric oxide together with carbon-centered radicals from N-nitrosamines by ultraviolet light irradiation [J].

Hiramoto, K ;

Ohkawa, T ;

Kikugawa, K .

FREE RADICAL RESEARCH, 2001, 35 (06) :803-813

[4] Significant reduction of carcinogenic compounds in tobacco smoke by the use of zeolite catalysts [J].

Meier, WM ;

Siegmann, K .

MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 33 (1-3) :307-310

[5] Thorium removal by different adsorbents [J].

Metaxas, M ;

Kasselouri-Rigopoulou, V ;

Galiatsatou, P ;

Konstantopoulou, C ;

Oikonomou, D .

JOURNAL OF HAZARDOUS MATERIALS, 2003, 97 (1-3) :71-82

[6]

MIRVISH SS, 1983, JNCI-J NATL CANCER I, V71, P629

[7]

MITCHELL PCH, 1991, CHEM IND-LONDON, P308

[8] Agricultural solid wastes for the removal of heavy metals: Adsorption of Cu(II) by coirpith carbon [J].

Namasivayam, C ;

Kadirvelu, K .

CHEMOSPHERE, 1997, 34 (02) :377-399

[9] IMPROVED GROUP DETERMINATION OF TOTAL N-NITROSO COMPOUNDS IN HUMAN GASTRIC-JUICE BY CHEMICAL DENITROSATION AND THERMAL-ENERGY ANALYSIS [J].

PIGNATELLI, B ;

RICHARD, I ;

BOURGADE, MC ;

BARTSCH, H .

ANALYST, 1987, 112 (07) :945-949

[10]

PRESTONMARTIN S, 1989, CANCER SURV, V8, P459

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