Polyaniline/Carbon black nanocomposites: The role of synthesis conditions on the morphology and properties

被引：21

作者：

da Silva, Luis M. G. ^{[1
]}

Lemos, Hugo G. ^{[1
]}

Santos, Sydney F. ^{[1
]}

Antunes, Renato A. ^{[1
]}

Venancio, Everaldo C. ^{[1
]}

机构：

[1] Univ Fed Abc, Ctr Engn Modelagem & Ciencias Sociais Aplicadas C, Av Estados 5001, BR-09210580 Santo Andre, SP, Brazil

来源：

MATERIALS TODAY COMMUNICATIONS | 2018年 / 16卷

基金：

巴西圣保罗研究基金会;

关键词：

Polyaniline; Carbon black; Nanocomposite; Morphology; HIGH-RATE CAPABILITY; CARBON-BLACK; CORROSION PROTECTION; GRAPHENE OXIDE; CONDUCTING POLYMERS; ANILINE; COATINGS; SUPERCAPACITORS; POLYMERIZATION; NANOPARTICLES;

D O I：

10.1016/j.mtcomm.2018.04.008

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The Polyaniline/Carbon black (PANI/CB) nanocomposites morphology and properties are extremely sensitive to the chemical synthesis conditions. This was observed when the structures obtained changed from globular-like to a multitude of globular-like and nanofiber structures by varying the aniline and CB concentration. The High-Resolution Transmission electron microscopy results showed that the globular-like structures consist of multi-core structures formed by CB particles covered by PANI. However, by increasing the monomer and CB concentration, while the monomer to CB mass weight ratio was kept constant, a PANI nanofibers network was also observed despite the formation of multi-core structures. These results suggest that PANI nucleation and growth processes proceed in two different ways, a homogenous nucleation and growth processes in the bulk solution and heterogeneous nucleation and growth processes at the CB surface. X-ray photoelectron spectroscopy (XPS) analysis showed that the in situ polymerization of aniline with the presence of CB may lead to the formation of PANI with higher degree of oxidation and higher degree of protonation. The hydrogen links from protonation may effectively stabilize the multi-core and nanofiber PANI network. Thermogravimetric analysis and differential scanning calorimetry results showed that the multi-core structure enhances the thermal stability of PANI/CB when compared to PANI.

引用

页码：14 / 21

页数：8

共 47 条

[1] Thermo-analyses of polyaniline and its derivatives [J].

Alves, William F. ;

Venancio, Everaldo C. ;

Leite, Fabio L. ;

Kanda, Darcy H. F. ;

Malmonge, Luiz F. ;

Malmonge, Jose A. ;

Mattoso, Luiz H. C. .

THERMOCHIMICA ACTA, 2010, 502 (1-2) :43-46

[2] Polyaniline, polypyrrole and poly(3,4-ethylenedioxythiophene) as additives of organic coatings to prevent corrosion [J].

Armelin, Elaine ;

Meneguzzi, Alvaro ;

Ferreira, Carlos A. ;

Aleman, Carlos .

SURFACE & COATINGS TECHNOLOGY, 2009, 203 (24) :3763-3769

[3] Polyaniline nanofibers: broadening applications for conducting polymers [J].

Baker, Christina O. ;

Huang, Xinwei ;

Nelson, Wyatt ;

Kaner, Richard B. .

CHEMICAL SOCIETY REVIEWS, 2017, 46 (05) :1510-1525

[4] Influence of the thickness and roughness of polyaniline coatings on corrosion protection of AA7075 aluminum alloy [J].

Bandeira, Rafael Marinho ;

van Drunen, Julia ;

Garcia, Amanda Cristina ;

Tremiliosi-Filho, Germano .

ELECTROCHIMICA ACTA, 2017, 240 :215-224

[5] Polyaniline and polyaniline-carbon black nanostructures as electrochemical capacitor electrode materials [J].

Bavio, Marcela A. ;

Acosta, Gerardo G. ;

Kessler, Teresita .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (16) :8582-8589

[6] Novel anticorrosion coatings prepared from polyaniline/graphene composites [J].

Chang, Chi-Hao ;

Huang, Tsao-Cheng ;

Peng, Chih-Wei ;

Yeh, Tzu-Chun ;

Lu, Hsin-I ;

Hung, Wei-I ;

Weng, Chang-Jian ;

Yang, Ta-I ;

Yeh, Jui-Ming .

CARBON, 2012, 50 (14) :5044-5051

[7] Conducting Polyaniline Nanoparticles and Their Dispersion for Waterborne Corrosion Protection Coatings [J].

Chen, Fei ;

Liu, Peng .

ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (07) :2694-2702

[8] A novel conducting nanocomposite obtained by p-anisidine and aniline with titanium(IV) oxide nanoparticles: Synthesis, Characterization, and Electrochemical properties [J].

Chouli, F. ;

Radja, I. ;

Morallon, E. ;

Benyoucef, A. .

POLYMER COMPOSITES, 2017, 38 :E254-E260

[9] Recent advances in polyaniline research: Polymerization mechanisms, structural aspects, properties and applications [J].

Ciric-Marjanovic, Gordana .

SYNTHETIC METALS, 2013, 177 :1-47

[10] Conducting polymers for corrosion protection: a review [J].

Deshpande, Pravin P. ;

Jadhav, Niteen G. ;

Gelling, Victoria J. ;

Sazou, Dimitra .

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2014, 11 (04) :473-494

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