Spectral and magnetic studies on manganese(II), cobalt(II) and nickel(II) complexes with Schiff bases

被引：119

作者：

Chandra, S ^{[1
]}

Kumar, U ^{[1
]}

机构：

[1] Univ Delhi, Zakir Husain Coll, Dept Chem, New Delhi 110002, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2005年 / 61卷 / 1-2期

关键词：

methyl cyclohexanone; thiosemicarbazone; magnetic susceptability; physico chemical;

D O I：

10.1016/j.saa.2004.03.036

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Mn(II), Co(II) and Ni(II) complexes of 2-methylcyclohexanone thiosemicarbazone(MCHTSC L-1) and 2-methylcyclohexanone-N-4-methyl-3-thiosemicarbazone (MCHMTSC L-2), general composition [M(L)(2)X-2] (where M = Mn(II), Co(II), Ni(II), L = L-1 or L-2 and X = Cl-, NO3-, amd 1/2SO(4)(2-)) have been synthesized and characterized by elemental analysis, magnetic susceptibility measurements, UV-vis, IR, EPR, and mass spectral studies. Various physico-chemical techniques suggest an octahedral geometry for all the complexes. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：219 / 224

页数：6

共 23 条

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