OsO4-catalyzed amination of silyl enol ethers:: enantioselective synthesis of α-amino ketones

被引:34
作者
Phukan, P [1 ]
Sudalai, A [1 ]
机构
[1] Natl Chem Lab, Div Organ Chem, Poona 411008, Maharashtra, India
关键词
D O I
10.1016/S0957-4166(98)00035-4
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Osmium tetroxide catalyzed asymmetric aminohydroxylation of silyl enol ethers using cinchona alkaloids as chiral ligands and chloramine-T as the nitrogen source affords enantiomerically pure alpha-amino ketones. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1001 / 1005
页数:5
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