Crystal Structure of the First Monomeric Organotellurium(IV) Oxide: Bis(2-dimethylaminomethylphenyl)tellurium(IV) Oxide

被引：13

作者：

Klapoetke, Thomas M. ^{[1
]}

Krumm, Burkhard ^{[1
]}

Scherr, Matthias ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 06期

关键词：

Crystal structure; donor-stabilization; tellurium; MOLECULAR-STRUCTURE; X-RAY; CHLORIDE; N; N-DIMETHYLBENZYLAMINE; COORDINATION; DERIVATIVES; TELLUROXIDE; TRIBROMIDE; REACTIVITY; FLUORIDE;

D O I：

10.1080/10426500902947476

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of (2-Me2NCH2C6H4)(2)TeO was determined by X-ray diffraction on a single crystal. The crystal symmetry is monoclinic, space group P2(1), with unit cell dimensions a = 9.2274(2), b = 10.1749(2), c = 11.5339(3) angstrom, beta = 109.952 degrees, V = 1017.90(4) angstrom(3) and Z = 2. The structure has been solved and refined down to wR(2) = 0.0625, using 3675 independent reflections. The compound consists of isolated molecules with two intramolecular Te center dot center dot center dot N interactions of 2.565(4) and 2.755(6) angstrom stabilizing the tellurium atom.

引用

页码：1347 / 1354

页数：8

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