Molybdenumhexacarbonyl-Mediated Imino-Carbonylative Acylation of NH-Sulfoximines with Aryl Iodides

被引：5

作者：

Baranwal, Siddharth ^{[1
]}

Gupta, Surabhi ^{[1
]}

Sabiah, Shahulhameed ^{[2
]}

Kandasamy, Jeyakumar ^{[1
]}

机构：

[1] Indian Inst Technol BHU, Dept Chem, Varanasi 221005, Uttar Pradesh, India

[2] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 8卷 / 12期

关键词：

Sulfoximine; Aryl halides; Carbonylation; Molybdenumhexacarbonyl; Catalyst-free; CARBON-MONOXIDE; AROYLATION; HALIDES; ARENES; CONVENIENT; MO(CO)(6); ARYLATION;

D O I：

10.1002/ajoc.201900526

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Development of a catalyst-free, robust and straightforward iminocarbonylation protocol for the synthesis of N-acyl sulfoximines from sulfoximines and aryl iodides in the presence of Mo(CO)(6) has been reported. Simple operation, broad substrate scope, wide functional group tolerance and excellent yields are the salient features of this work.

引用

页码：2218 / 2227

页数：10

共 56 条

[1] Palladium(0)-Catalyzed Carbonylative One-Pot Synthesis of N-Acylguanidines [J].

Akerbladh, Linda ;

Schembri, Luke S. ;

Larhed, Mats ;

Odell, Luke R. .

JOURNAL OF ORGANIC CHEMISTRY, 2017, 82 (23) :12520-12529

[2] Sulfoximinocarbonylation of aryl halides using heterogeneous Pd/C catalyst [J].

Bala, Balasubramanian Devi ;

Sharma, Nidhi ;

Sekar, Govindasamy .

RSC ADVANCES, 2016, 6 (99) :97152-97159

[3]

Beller M., 2013, TRANSITION METAL CAT

[4] Fluorinated sulfoximines: syntheses, properties and applications [J].

Bizet, Vincent ;

Kowalczyk, Rafal ;

Bolm, Carsten .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (08) :2426-2438

[5] N-Trifluoromethylthiolated Sulfoximines [J].

Bohnen, Christian ;

Bolm, Carsten .

ORGANIC LETTERS, 2015, 17 (12) :3011-3013

[6] Straightforward Strategies for the Preparation of NH-Sulfoximines: A Serendipitous Story [J].

Bull, James A. ;

Degennaro, Leonardo ;

Luisi, Renzo .

SYNLETT, 2017, 28 (19) :2525-2538

[7] Palladium-catalyzed α-arylation of sulfoximines [J].

Cho, GY ;

Bolm, C .

ORGANIC LETTERS, 2005, 7 (07) :1351-1354

[8] Direct C(sp2)-H Hydroxylation of Arenes with Palladium(II)/Oxygen Using Sulfoximines as a Recyclable Directing Group [J].

Das, Prasenjit ;

Guin, Joyram .

CHEMCATCHEM, 2018, 10 (11) :2370-2373

[9] Palladium-catalyzed N-vinylation of sulfoximines [J].

Dehli, JR ;

Bolm, C .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (24) :8518-8520

[10]

Franck-Neumann M., 1988, ORGANOMETALLICS ORGA

← 1 2 3 4 5 6 →