Controlled Sculpture of Black Phosphorus Nanoribbons

被引：133

作者：

Das, Paul Masih ^{[1
]}

Danda, Gopinath ^{[1
,2
]}

Cupo, Andrew ^{[3
]}

Parkin, William M. ^{[1
]}

Liang, Liangbo ^{[4
]}

Kharche, Neerav ^{[3
]}

Ling, Xi ^{[5
]}

Huang, Shengxi ^{[5
]}

Dresselhaus, Mildred S. ^{[5
]}

Meunier, Vincent ^{[3
]}

Drndic, Marija ^{[1
]}

机构：

[1] Univ Penn, Dept Phys & Astron, Philadelphia, PA 19104 USA

[2] Univ Penn, Dept Elect & Syst Engn, Philadelphia, PA 19104 USA

[3] Rensselaer Polytech Inst, Dept Phys Appl Phys & Astron, Troy, NY 12180 USA

[4] Oak Ridge Natl Lab, Ctr Nanophase Mat Sci, Oak Ridge, TN 37831 USA

[5] MIT, Dept Elect Engn & Comp Sci, Cambridge, MA 02139 USA

来源：

ACS NANO | 2016年 / 10卷 / 06期

关键词：

few-layer black phosphorus; phosphorene; nanoribbon; nanopore; armchair; zigzag; INPLANE THERMAL-CONDUCTIVITY; FIELD-EFFECT TRANSISTORS; ELECTRON-BEAM; GRAPHENE NANORIBBONS; ATOMIC-STRUCTURE; TRANSPORT; EXFOLIATION; PASSIVATION; MICROSCOPE; RESOLUTION;

D O I：

10.1021/acsnano.6b02435

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Black phosphorus (BP) is a highly anisotropic allotrope of phosphorus with great promise for fast functional electronics and optoelectronics. We demonstrate the controlled structural modification of few-layer BP along arbitrary crystal directions with sub-nanometer precision for the formation of few-nanometer-wide armchair and zigzag BP nanoribbons. Nanoribbons are fabricated, along with nanopores and nanogaps, using a combination of mechanical-liquid exfoliation and in situ transmission electron microscopy (TEM) and scanning TEM nano sculpting. We predict that the few-nanometer-wide BP nanoribbons realized experimentally possess clear one-dimensional quantum confinement, even when the systems are made up of a few layers. The demonstration of this procedure is key for the development of BP-based electronics, optoelectronics, thermoelectrics, and other applications in reduced dimensions.

引用

页码：5687 / 5695

页数：9

共 51 条

[1] [Anonymous], 1997, P INT SCH PHYS
[2] Air-Stable Transport in Graphene-Contacted, Fully Encapsulated Ultrathin Black Phosphorus-Based Field-Effect Transistors
Avsar, Ahmet
Vera-Marun, Ivan J.
Tan, Jun You
Watanabe, Kenji
Taniguchi, Takashi
Castro Neto, Antonio H.
Oezyilmaz, Barbaros
[J]. ACS NANO, 2015, 9 (04) : 4138 - 4145
[3] PROJECTOR AUGMENTED-WAVE METHOD
BLOCHL, PE
[J]. PHYSICAL REVIEW B, 1994, 50 (24): : 17953 - 17979
[4] Isolation and characterization of few-layer black phosphorus
Castellanos-Gomez, Andres
Vicarelli, Leonardo
Prada, Elsa
Island, Joshua O.
Narasimha-Acharya, K. L.
Blanter, Sofya I.
Groenendijk, Dirk J.
Buscema, Michele
Steele, Gary A.
Alvarez, J. V.
Zandbergen, Henny W.
Palacios, J. J.
van der Zant, Herre S. J.
[J]. 2D MATERIALS, 2014, 1 (02):
[5] Anisotropic exciton Stark shift in black phosphorus
Chaves, A.
Low, Tony
Avouris, P.
Cakir, D.
Peeters, F. M.
[J]. PHYSICAL REVIEW B, 2015, 91 (15)
[6] Tunable Transport Gap in Phosphorene
Das, Saptarshi
Zhang, Wei
Demarteau, Marcel
Hoffmann, Axel
Dubey, Madan
Roelofs, Andreas
[J]. NANO LETTERS, 2014, 14 (10) : 5733 - 5739
[7] Van der Waals density functional for general geometries -: art. no. 246401
Dion, M
Rydberg, H
Schröder, E
Langreth, DC
Lundqvist, BI
[J]. PHYSICAL REVIEW LETTERS, 2004, 92 (24) : 246401 - 1
[8] Quantitative characterisation of chemical inhomogeneities in (Al)under-bar-Ag using high-resolution Z-ontrast STEM
Erni, R
Heinrich, H
Kostorz, G
[J]. ULTRAMICROSCOPY, 2003, 94 (02) : 125 - 133
[9] Favron A, 2015, NAT MATER, V14, P826, DOI [10.1038/NMAT4299, 10.1038/nmat4299]
[10] Electron beam nanosculpting of suspended graphene sheets
Fischbein, Michael D.
Drndic, Marija
[J]. APPLIED PHYSICS LETTERS, 2008, 93 (11)

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