A neutral dicopper(III) bis(μ-oxo) complex from a copper(I) ethylene iminophosphanamide and O2

被引:54
作者
Straub, BF [1 ]
Rominger, F [1 ]
Hofmann, P [1 ]
机构
[1] Heidelberg Univ, Inst Organ Chem, D-69120 Heidelberg, Germany
关键词
D O I
10.1039/b004173o
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The copper(i) ethylene complex [(Bu2P)-P-t(NSiMe3)(2)-kappa(2)N]Cu(eta(2)-C2H4) reacts with O-2, yielding an uncharged dinuclear copper(iii) bis(mu-oxo) species, which has been fully characterized, e.g. by single-crystal X-ray diffraction.
引用
收藏
页码:1611 / 1612
页数:2
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