Effect of thickness on the microstructural, optoelectronic and morphological properties of electron beam evaporated ZnTe films

被引:29
作者
Balu, A. R. [3 ,4 ]
Nagarethinam, V. S. [3 ,4 ]
Thayumanavan, A. [3 ,4 ]
Murali, K. R. [1 ,2 ,4 ]
Sanjeeviraja, C. [1 ,2 ,4 ]
Jayachandran, M. [1 ,2 ,4 ]
机构
[1] Cent Electrochem Res Inst, Electrochem Mat Sci Div, Karaikkudi 630006, Tamil Nadu, India
[2] CSIR, Electrochem Mat Sci Div, New Delhi, India
[3] AVVM Sri Pushpam Coll, Dept Phys, Thanjavur, India
[4] Alagappa Univ, Dept Phys, Karaikkudi 630003, Tamil Nadu, India
关键词
II-VI; Semiconductor; Thin films; ZnTe; THIN-FILMS; OPTICAL-PROPERTIES; GLASS; EPITAXY; CDTE; SPECTROSCOPY; DEPENDENCE; INTERLAYER; SILICON; SWITCH;
D O I
10.1016/j.jallcom.2010.04.191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
ZnTe films of different thicknesses were deposited on glass substrates at a substrate temperature of 300 degrees C. The thickness of the films varied in the range of 110-320 nm. The films exhibited cubic structure with preferential orientation in the (1 1 1) direction. A very high value of absorption co-efficient (10(4)cm(-1)) is observed. Band gap values in the range between 2.23 and 2.38 eV are observed when the film thickness was varied between 320 and 110 nm, respectively. The refractive index values are found to vary between 2.68 and 2.90 for the films of different thicknesses. It has been observed that the conductivity increases continuously with temperature as well as with thickness. Laser Raman spectra showed the presence of peaks at 206.8 and 411.2 cm(-1) corresponding to the first order and second order LO phonon of monophase ZnTe films. PL analysis confirmed the formation of monophase ZnTe films with nano grains. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:434 / 438
页数:5
相关论文
共 32 条
[1]  
Chang JH, 2002, PHYS STATUS SOLIDI B, V229, P995, DOI 10.1002/1521-3951(200201)229:2<995::AID-PSSB995>3.0.CO
[2]  
2-G
[3]  
Ebina A., 1982, J. Crystal Growth, V59, P432
[4]   Structural dependence of dc electrical properties of physically deposited CdTe thin films [J].
ElKadry, N ;
Ashour, A ;
Mahmoud, SA .
THIN SOLID FILMS, 1995, 269 (1-2) :112-116
[5]   Optical gate realization by laser crossing in thin-film semiconductors on glass [J].
Erlacher, A ;
Ullrich, B ;
Konopinski, RJ ;
Haugan, HJ .
Optical Components and Materials II, 2005, 5723 :179-186
[6]   All-optical digitizing of laser transmission through thin-film GaAs on glass [J].
Erlacher, A ;
Ullrich, B .
SEMICONDUCTOR SCIENCE AND TECHNOLOGY, 2004, 19 (03) :L9-L12
[7]   Low-power all-optical switch by superposition of red and green laser irradiation in thin-film cadmium sulfide on glass [J].
Erlacher, A ;
Miller, H ;
Ullrich, B .
JOURNAL OF APPLIED PHYSICS, 2004, 95 (05) :2927-2929
[8]   Observation of ultra-broadband terahertz emission from ZnTe films grown by metaloganic vapor epitaxy [J].
Guo, Qixin ;
Kume, Yusuke ;
Fukuhara, Yuji ;
Tanaka, Tooru ;
Nishio, Mitsuhiro ;
Ogawa, Hiroshi ;
Hiratsuka, Masahiro ;
Tani, Masahiko ;
Hangyo, Masanori .
SOLID STATE COMMUNICATIONS, 2007, 141 (04) :188-191
[9]   An investigation into the effect of ionic species on the formation of ZnTe from a citric acid electrolyte [J].
Ishizaki, T ;
Saito, N ;
Takai, O ;
Asakura, S ;
Goto, K ;
Fuwa, A .
ELECTROCHIMICA ACTA, 2005, 50 (16-17) :3509-3516
[10]   Electrodeposition of ZnTe film with high current efficiency at low overpotential from a citric acid bath [J].
Ishizaki, T ;
Ohtomo, T ;
Fuwa, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2004, 151 (03) :C161-C167