Methyltrioxorhenium/pyrazole - A highly efficient catalyst for the epoxidation of olefins

被引：139

作者：

Herrmann, WA ^{[1
]}

Kratzer, RM ^{[1
]}

Ding, H ^{[1
]}

Thiel, WR ^{[1
]}

Glas, H ^{[1
]}

机构：

[1] Tech Univ Munchen, Inst Anorgan Chem, D-85747 Garching, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 555卷 / 02期

关键词：

methyltrioxorhenium; olefin epoxidation; pyrazole; catalysis;

D O I：

10.1016/S0022-328X(97)00784-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A biphasic system consisting of 35% H2O2 and methyltrioxorhenium(VII)/pyrazole in CH2Cl2 catalyzes the epoxidation of a wide range of olefins in excellent yields. Both the reactivity and selectivity of the new catalytic surpasses all known MTO/Lewis base catalysts. The considerable ligand accelerating effect observed here is attributed to the stability of pyrazole against oxidation. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：293 / 295

页数：3

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