An efficient and highly regioselective fluorination of aziridines using BF3•OEt2 as fluorine source

被引：31

作者：

Ding, CH

Dai, LX

Hou, XL

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

来源：

SYNLETT | 2004年 / 12期

关键词：

aziridines; fluorination; BF3 center dot OEt2; ring-opening reaction; ss-fluoro amine;

D O I：

10.1055/s-2004-831319

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-Fluoro amines were prepared from the reaction of aziridines and boron trifluoride in high regioselectivity and in high yield. All three fluorine atoms of (BF3OEt2)-O-. were incorporated into the products when it reacted with aziridines.

引用

页码：2218 / 2220

页数：3

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