2-Aminobiphenyl Palladacycles: The "Most Powerful" Precatalysts in C-C and C-Heteroatom Cross-Couplings

被引：142
作者：
Bruneau, Alexandre [1 ]
Roche, Maxime [1 ]
Alami, Mouad [1 ]
Messaoudi, Samir [1 ]
机构：
[1] Univ Paris Sud, CNRS, Lab Chim Therapeut,BioCIS UMR 8076, Equipe Labellisee Ligue Canc,LabEx LERMIT,Fac Pha, F-92296 Chatenay Malabry, France
来源：
ACS CATALYSIS | 2015年 / 5卷 / 02期
关键词：
catalysis; palladacycles; precatalysts; C-C and C-heteroatom bonds formation; cross-couplings; CATALYZED ALPHA-ARYLATION; CARBAZOLE ALKALOIDS; FLOW CHEMISTRY; H ARYLATION; PALLADIUM; SECONDARY; BOND; ARYL; ESTERS; MILD;
D O I：
10.1021/cs502011x
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
New approaches to the Pd-catalysis employing palladacycle precatalysts have been recently developed. Breakthroughs in this area using 2-aminobiphenyl palladacycle precatalysts are highlighted. High reactivity and selectivity are achieved for the C-C and C-heteroatom bond formation under mild reaction conditions.
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收藏
页码：1386 / 1396
页数：11
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