Solvothermal Synthesis and Structure of Two New Borates Containing [B7O9(OH)5]2- and [B12O18(OH)6]6- Clusters

被引：9
|
作者：
Zhang, Tian-Jiao [1 ]
Pan, Rui [1 ]
He, Huan [1 ]
Yang, Bai-Feng [1 ]
Yang, Guo-Yu [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 02期
关键词：
Borate; Solvothermal synthesis; Oxoboron cluster; Structure; ISOLATED POLYBORATE ANIONS; NONLINEAR-OPTICAL CRYSTAL; OPEN-FRAMEWORK; METAL-COMPLEXES; BO3; UNITS; HEPTABORATE; PENTABORATE; CATIONS;
D O I：
10.1007/s10876-015-0962-y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal borates, K[B7O9(OH)(5)]center dot Hen (1, en = enthylenediamine) and Na2Cs4Ba2[B12O18(OH)(6)]center dot 4(OH) (2) have been synthesized under solvothermal conditions. Their structures were determined by the single crystal X-ray diffraction and were further characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and powder X-ray diffraction, respectively. 1 crystallizes in the triclinic system, P-1 space group, a = 7.7152(6), b = 8.4057(6), c = 12.1319(10) , alpha = 92.505(6), beta = 98.944(7), gamma = 103.825(6)A degrees, Z = 2. 2 crystallizes in the orthorhombic system, Pmn2(1) space group, a = 12.6972(6) , b = 13.7037(6) , c = 9.4968(5) , Z = 2. Compound 1 consists of isolated [B7O9(OH)(5)](2-) clusters which are held together through H-bonding interactions and K atoms to form a 3-D supramolecular framework. For 2, bowl-like isolated [B12O18(OH)(6)](6-) clusters were linked together to form a 3-D framework by different metal ions and H-bond system.
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收藏
页码：625 / 633
页数：9
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