Solvothermal Synthesis and Structure of Two New Borates Containing [B7O9(OH)5]2- and [B12O18(OH)6]6- Clusters

被引：9
|
作者：
Zhang, Tian-Jiao [1 ]
Pan, Rui [1 ]
He, Huan [1 ]
Yang, Bai-Feng [1 ]
Yang, Guo-Yu [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem, MOE Key Lab Cluster Sci, Beijing 100081, Peoples R China
来源：
JOURNAL OF CLUSTER SCIENCE | 2016年 / 27卷 / 02期
关键词：
Borate; Solvothermal synthesis; Oxoboron cluster; Structure; ISOLATED POLYBORATE ANIONS; NONLINEAR-OPTICAL CRYSTAL; OPEN-FRAMEWORK; METAL-COMPLEXES; BO3; UNITS; HEPTABORATE; PENTABORATE; CATIONS;
D O I：
10.1007/s10876-015-0962-y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal borates, K[B7O9(OH)(5)]center dot Hen (1, en = enthylenediamine) and Na2Cs4Ba2[B12O18(OH)(6)]center dot 4(OH) (2) have been synthesized under solvothermal conditions. Their structures were determined by the single crystal X-ray diffraction and were further characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis and powder X-ray diffraction, respectively. 1 crystallizes in the triclinic system, P-1 space group, a = 7.7152(6), b = 8.4057(6), c = 12.1319(10) , alpha = 92.505(6), beta = 98.944(7), gamma = 103.825(6)A degrees, Z = 2. 2 crystallizes in the orthorhombic system, Pmn2(1) space group, a = 12.6972(6) , b = 13.7037(6) , c = 9.4968(5) , Z = 2. Compound 1 consists of isolated [B7O9(OH)(5)](2-) clusters which are held together through H-bonding interactions and K atoms to form a 3-D supramolecular framework. For 2, bowl-like isolated [B12O18(OH)(6)](6-) clusters were linked together to form a 3-D framework by different metal ions and H-bond system.
引用
收藏
页码：625 / 633
页数：9
相关论文
共 50 条
  • [1] Solvothermal Synthesis and Structure of Two New Borates Containing [B7O9(OH)5]2− and [B12O18(OH)6]6− Clusters
    Tian-Jiao Zhang
    Rui Pan
    Huan He
    Bai-Feng Yang
    Guo-Yu Yang
    Journal of Cluster Science, 2016, 27 : 625 - 633
  • [2] Two new borates containing the first examples of large isolated polyborate anions:: Chain [B7O9(OH)5]2- and ring [B14O20(OH)6]4-
    Liu, ZH
    Li, LQ
    Zhang, WJ
    INORGANIC CHEMISTRY, 2006, 45 (04) : 1430 - 1432
  • [3] Two New Borates Made of [B5O6(OH)4]- and [B5O10(OH)]6- Clusters, Accompanying a Novel In Situ Organic Reaction
    Huang, Guang
    Pan, Rui
    He, Huan
    Yang, Bai-Feng
    Yang, Guo-Yu
    JOURNAL OF CLUSTER SCIENCE, 2015, 26 (06) : 2023 - 2032
  • [4] Crystal structure of Rb6[B12O18(OH)6]•2H2O
    Qiu, Qi-Ming
    Yan, Li
    Song, Jian-Biao
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 971 - +
  • [5] A novel mixed-metal borate with large [B12O18(OH)6]6- motif: Synthesis, structure and property
    Wei, Li
    Pan, Jie
    Xue, Zhen-Zhen
    Wang, Guo-Ming
    Wang, Ying-Xia
    SOLID STATE SCIENCES, 2018, 75 : 9 - 13
  • [6] Solvothermal Syntheses and Crystal Structures of Two Novel Borates: [(CH3)3NH][B5O6(OH)4] and Na2[H2TMED][B7O9(OH)5]2
    Li, Ping
    Li, Lian-Qing
    Huang, Hong-Sheng
    Liu, Zhi-Hong
    JOURNAL OF CLUSTER SCIENCE, 2014, 25 (04) : 893 - 903
  • [7] Solvothermal Syntheses and Crystal Structures of Two Novel Borates: [(CH3)3NH][B5O6(OH)4] and Na2[H2TMED][B7O9(OH)5]2
    Ping Li
    Lian-Qing Li
    Hong-Sheng Huang
    Zhi-Hong Liu
    Journal of Cluster Science, 2014, 25 : 893 - 903
  • [8] A new polyborate anion, [B7O9(OH)6]3- : Self assembly, XRD and thermal properties of s-fac-[Co(dien)2][B7O9(OH)6]•9H2O
    Altahan, Mohammed A.
    Beckett, Michael A.
    Coles, Simon J.
    Horton, Peter N.
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 59 : 95 - 98
  • [9] Two New Borates Made of [B5O6(OH)4]− and [B5O10(OH)]6− Clusters, Accompanying a Novel In Situ Organic Reaction
    Guang Huang
    Rui Pan
    Huan He
    Bai-Feng Yang
    Guo-Yu Yang
    Journal of Cluster Science, 2015, 26 : 2023 - 2032
  • [10] Synthesis and structure of a new heptaborate oxoanion isomer:: B7O9(OH)52-
    Schubert, David M.
    Visi, Mandana Z.
    Khan, Saeed
    Knobler, Carolyn B.
    INORGANIC CHEMISTRY, 2008, 47 (11) : 4740 - 4745
12345