Study of air pollutants in Hong Kong using energy dispersive X-ray fluorescence

Airborne particulate samples were collected from various reference sites in Hong Kong and the energy dispersive Xray fluorescence (EDXRF) intensities for 19 chemical elements were recorded. Principal component analysis (PCA) was employed so that the variances of these 19 original variables were captured by a few new indices called principal components or PCs. Data points for similar sources were automatically grouped together in a plot of the first three PCs (PC plot). Data for the monitoring site Mong Kok were located within the area defined by vehicular emissions. As such, the main air pollutant at this site was concluded to originate from vehicular emissions. A fraction of data for the Causeway Bay monitoring site also fell into this same identified area, so the main air pollutant could also be vehicular emissions. Some of the data located either on or outside the border can be explained in terms of meteorology. (C) 2003 Elsevier Science Ltd. All rights reserved.