Visible-Light-Induced Cyclization of Electron-Enriched Phenyl Benzyl Sulfides: Synthesis of Tetrahydrofurans and Tetrahydropyrans

被引：5
作者：
Li, Wei [1 ,2 ]
Yang, Chao [1 ]
Gao, Guo-Lin [1 ]
Xia, Wujiong [1 ]
机构：
[1] Harbin Inst Technol, Shenzhen Grad School, State Key Lab Urban Water Resource & Environm, Harbin 150080, Peoples R China
[2] Harbin Univ Commerce, Key Lab Food Sci & Engn, Harbin 150076, Peoples R China
来源：
SYNLETT | 2016年 / 27卷 / 09期
关键词：
photocatalysis; sulfides; cyclization; tetrahydrofurans; tetrahydropyrans; C-H BONDS; STEREOSELECTIVE-SYNTHESIS; PHOTOREDOX CATALYSIS; RADICAL CATIONS; O-GLYCOSYLATION; METAL-FREE; ACTIVATION; ALCOHOLS; OXYGEN; FUNCTIONALIZATION;
D O I：
10.1055/s-0035-1561393
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new approach to the preparation of tetrahydrofurans and tetrahydropyrans through a photoredox catalytic process is described. The introduction of a phenylsulfanyl auxiliary group permits the substrates to be readily oxidized to form cationic intermediates for sequential intramolecular cyclization. The method features mild reaction conditions and operational simplicity.
引用
收藏
页码：1391 / 1396
页数：6
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