New metal complexes supported on Fe3O4 magnetic nanoparticles as recoverable catalysts for selective oxidation of sulfides to sulfoxides

被引：30

作者：

Hajjami, Maryam ^{[1
]}

Kolivand, Somaye ^{[1
]}

机构：

[1] Ilam Univ, Fac Sci, Dept Chem, POB 69315516, Ilam, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2016年 / 30卷 / 05期

关键词：

Zr(IV) complex of Fe3O4; Cu(II) complex of Fe3O4; magnetic nanoparticles; sulfoxides; EFFICIENT CATALYST; HYDROGEN-PEROXIDE; HETEROGENEOUS CATALYST; REUSABLE NANOCATALYST; COPPER(II); ACID; SILICA; SULFONES; AMBIENT; MCM-41;

D O I：

10.1002/aoc.3429

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Fe3O4 nanoparticles were coated with aminopropyltriethoxysilane and subsequently reacted with isatin to obtain imine-bonded Fe3O4 nanoparticles. The addition of ZrOCl2 center dot 8H(2)O or CuCl2 led to the formation of complexes of Zr(IV)/isatin@Fe3O4 or Cu (II)/isatin@Fe3O4 as new magnetically separable catalysts. The synthesized catalysts were characterized using various techniques. These catalysts are shown to be efficient for chemo-selective oxidation of sulfides to sulfoxides using hydrogen peroxide as oxidative agent. This system has many advantages, such as excellent level of reusability of magnetic catalysts, high yields, simplicity of separation of catalysts using an external magnet, environmental benignity and ease of handling. Copyright (C) 2016 John Wiley & Sons, Ltd.

引用

页码：282 / 288

页数：7

共 51 条

[1] Copper modified spherical MCM-41 nano particles: an efficient catalyst for the three-component coupling of aldehydes, amines and alkynes in solvent-free conditions [J].

Abdollahi-Alibeik, Mohammad ;

Moaddeli, Ali .

RSC ADVANCES, 2014, 4 (75) :39759-39766

[2] Cobalt salophen complex supported on imidazole functionalized magnetic nanoparticles as a recoverable catalyst for oxidation of alkenes [J].

Afshari, Mozhgan ;

Gorjizadeh, Maryam ;

Nazari, Simin ;

Naseh, Mohammad .

JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2014, 363 :13-17

[3] Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride [J].

Bahrami, K .

TETRAHEDRON LETTERS, 2006, 47 (12) :2009-2012

[4] Selective oxidation of sulfides to sulfoxides by a molybdate-based catalyst using 30% hydrogen peroxide [J].

Bayat, Ahmad ;

Shakourian-Fard, Mehdi ;

Hashemi, Mohammad Mahmoodi .

CATALYSIS COMMUNICATIONS, 2014, 52 :16-21

[5] Zirconium(IV) compounds as efficient catalysts for synthesis of α-aminophosphonates [J].

Bhagat, Srikant ;

Chakraborti, Asit K. .

JOURNAL OF ORGANIC CHEMISTRY, 2008, 73 (15) :6029-6032

[6] Selective catalytic reduction of nitric oxide with ammonia over zirconium-doped copper/ZSM-5 catalysts [J].

Bin, Feng ;

Song, Chonglin ;

Lv, Gang ;

Song, Jinou ;

Wu, Shaohua ;

Li, Xiaodong .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 150 :532-543

[7] Use of copper(II)/diamine catalysts in the desymmetrisation of meso-diols and asymmetric Henry reactions: comparison of (-)-sparteine and (+)-sparteine surrogates [J].

Canipa, Steven J. ;

Stute, Annika ;

O'Brien, Peter .

TETRAHEDRON, 2014, 70 (40) :7395-7403

[8] APPLICATIONS OF SULFOXIDES TO ASYMMETRIC-SYNTHESIS OF BIOLOGICALLY-ACTIVE COMPOUNDS [J].

CARRENO, MC .

CHEMICAL REVIEWS, 1995, 95 (06) :1717-1760

[9] Chiral copper(II) bisoxazoline covalently anchored to silica and mesoporous MCM-41 as a heterogeneous catalyst for the enantioselective Friedel-Crafts hydroxyalkylation [J].

Corma, A ;

García, H ;

Moussaif, A ;

Sabater, MJ ;

Zniber, R ;

Redouane, A .

CHEMICAL COMMUNICATIONS, 2002, (10) :1058-1059

[10] Enantioselective oxidation of sulfides with H2O2 catalyzed by a pre-formed manganese complex [J].

Dai, Wen ;

Li, Guosong ;

Wang, Lianyue ;

Chen, Bo ;

Shang, Sensen ;

Lv, Ying ;

Gao, Shuang .

RSC ADVANCES, 2014, 4 (87) :46545-46554

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