Experimental and theoretical studies on pyrolysis of O-acetyl derivatives of β-phenylcinnamaldehyde and benzaldehyde oximes

被引：0

作者：

Mohamed, MAA ^{[1
]}

Siedlecka, U ^{[1
]}

Suwinski, J ^{[1
]}

机构：

[1] Silesian Tech Univ, Inst Organ Chem & Technol, PL-44100 Gliwice, Poland

来源：

POLISH JOURNAL OF CHEMISTRY | 2003年 / 77卷 / 05期

关键词：

aldoxime-O-acetates; cyclization; elimination; PM3; calculations;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thermal behavior of beta-phenylcinnamaldehyde and benzaldehyde oxime o-acetyl derivatives was studied experimentally and theoretically by the semi-empirical PM3 method. Intramolecular pericyclic mechanisms were proposed for the reactions of the E-isomers, intramolecular catalytic polar mechanism for elimination of acetic acid from the Z-isomers.

引用

页码：577 / 590

页数：14

共 50 条

[1] SPECTROPHOTOMETRIC DETERMINATION OF ACETYL GROUPS IN O-ACETYL DERIVATIVES OF SACCHARIDES
BILIK, V
KUCAR, S
CHEMICKE ZVESTI, 1968, 22 (08): : 622 - &
[2] Theoretical studies on pyrolysis mechanism of O-acetyl-xylopyranose
Huang, Jin-Bao
Liu, Chao
Tong, Hong
Li, Wei-Min
Wu, Dan
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology, 2013, 41 (03): : 285 - 293
[3] O-ACETYL DERIVATIVES OF N-ACETYLMURAMIC ACID
OSAWA, T
SINAY, P
HALFORD, M
JEANLOZ, RW
BIOCHEMISTRY, 1969, 8 (08) : 3369 - &
[4] N-(D-RIBOPYRANOSYL)-PARA-NITROANILINE AND ITS O-ACETYL AND N,O-ACETYL DERIVATIVES
PISKORSKA, D
SOKOLOWSKI, J
POLISH JOURNAL OF CHEMISTRY, 1979, 53 (05) : 1001 - 1009
[5] Experimental and theoretical studies of pyrolysis of chrysophanol and its derivatives
Jia, Liangyuan
Yang, Jiuzhong
Zhang, Lidong
Zhang, Feng
Qi, Fei
Fan, Haiyan
Cai, Jibao
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 2013, 100 : 237 - 244
[6] O-ACETYL AND N-ACETYL DERIVATIVES OF 3-ACETOXYPYRIDONE-2
KROWICKI, K
ROCZNIKI CHEMII, 1976, 50 (12): : 2193 - 2196
[7] STUDIES ON DISTRIBUTION OF O-ACETYL GROUPS IN PINE GLUCOMANNAN
KENNE, L
ROSELL, KG
SVENSSON, S
CARBOHYDRATE RESEARCH, 1975, 44 (01) : 69 - 76
[8] PHOTOOXYGENATION OF POLYHYDROXYALKYLFURANS - REARRANGEMENT OF O-ACETYL DERIVATIVES .2.
APARICIO, FJL
DIAZ, RR
GARCIA, JI
CALVOFLORES, FG
CARBOHYDRATE RESEARCH, 1986, 148 (02) : 235 - 247
[9] STUDIES ON KETENE AND ITS DERIVATIVES .92. REACTION OF DIKETENE WITH BENZALDEHYDE, CINNAMALDEHYDE, AND BETA-PHENYLCINNAMALDEHYDE
KATO, T
CHIBA, T
SATO, M
CHEMICAL & PHARMACEUTICAL BULLETIN, 1978, 26 (12) : 3877 - 3879
[10] Intramolecular iron-catalyzed transannulation of furans with O-acetyl oximes: synthesis of functionalized pyrroles
Makarov, Anton S.
Fadeev, Alexander A.
Uchuskin, Maxim G.
ORGANIC CHEMISTRY FRONTIERS, 2021, 8 (23): : 6553 - 6560

← 1 2 3 4 5 →