Epoxidation and cyclopropanation of 2-silyl-3-alkenols. A study of 1,2-asymmetric induction

被引：22

作者：

Landais, Y

ParraRapado, L

机构：

[1] Institut de Chimie Organique, Université de Lausanne, Collège Propédeutique

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 08期

关键词：

D O I：

10.1016/0040-4039(95)02386-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Epoxidation and cyclopropanation of 2-silyl-3-alkenols have been shown to occur with high 1,2-stereocontrol through substrate directable reactions. Both syn and anti epoxides are thus available from E and Z-alkylsilanes. This contrasts with the results usually observed for allylsilanes lacking a coordinating group.

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页码：1205 / 1208

页数：4

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