Bis(1,10-phenanthroline-κ2N,N′)copper(I) chloridobis(1,10-phenanthroline-κ2N,N′) copper(II) hexacosaoxidooctamolybdate(VI) dihydrate

被引：3

作者：

Wang, Wen-Ju

Xu, Lin ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometallate Sci, Minist Educ, Changchun 130024, Peoples R China

[2] Baicheng Teachers Coll, Dept Chem, Baicheng 137000, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536807030450

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [(CuCl)-Cl-II(C12H8N2)(2)](2)[Cu-I(C12H8N2)(2)](2)[Mo8O26]center dot 2H(2)O, features a centrosymmetric alpha-type octamolybdate anion, two complex copper counter-cations with Cu in oxidation states +II and +I, and two water molecules of crystallization. The Cu-II ion exhibits a distorted CuN4Cl square-pyramidal coordination, whereas the Cu-I ion is in a distorted tetrahedral CuN4 coordination. The anions, cations and uncoordinated water molecules are linked into a three-dimensional network by O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds.

引用

页码：M1993 / U1844

页数：19

共 5 条

[1] A three-dimensional bimetallic oxide constructed from octamolybdate clusters and copper-ligand cation polymer subunits. A comment on the stability of the octamolybdate isomers [J].