Comparison of mechanisms for the direct, gas phase, partial oxidation of methane to methanol

被引：5

作者：

Turan, Evren M. ^{[1
]}

van Steen, Eric ^{[2
]}

Moller, Klaus P. ^{[2
]}

机构：

[1] Norwegian Univ Sci & Technol, Dept Chem Engn, NTNU, N-7491 Trondheim, Norway

[2] Univ Cape Town, Dept Chem Engn, Cape Town, South Africa

来源：

CHEMICAL ENGINEERING SCIENCE | 2021年 / 241卷

关键词：

Methane; Methanol; partial oxidation; DIRECT CONVERSION; SLOW COMBUSTION; HIGH-PRESSURES; FLOW REACTOR; NATURAL-GAS; KINETICS; OXYGEN; TECHNOLOGIES; OPTIMIZATION; CHEMICALS;

D O I：

10.1016/j.ces.2021.116718

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Numerous mechanisms have been proposed for the direct, homogeneous, partial oxidation of methane to methanol system. No thorough comparison of them to experimental data, and to each other, has been reported. In this work six mechanisms are tested against over 200 operating points from published liter-ature. All the examined mechanisms are found to be inaccurate, with the most accurate mechanism, M-Vedeneev; C1 (Arutyunov et al., 1996), having an average selectivity error of 17%. In addition, it was found that some mechanisms showed behaviour that was not observed in the literature and were deemed unsuitable for the reaction system. As such all of the available mechanisms do not adequately describe the gas phase methane to methanol system. (C) 2021 Elsevier Ltd. All rights reserved.

引用

页数：9

共 63 条

[1]

Arutyunov V, 2014, DIRECT METHANE TO METHANOL: FOUNDATIONS AND PROSPECTS OF THE PROCESS, P1

[2]

Arutyunov V.S, 2017, METHANOL SCI ENG, P129, DOI [10.1016/B978-0-444-63903-5.00006-6, DOI 10.1016/B978-0-444-63903-5.00006-6]

[3] The interplay of catalytic and gas-phase stages at oxidative conversion of methane: A review [J].

Arutyunov, Vladimir S. ;

Strekova, Ludmila N. .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2017, 426 :326-342

[4] Partial alkane oxidation kinetics at high pressures: Methane oxidation in stainless steel and quartz reactors [J].

Arutyunov, VS ;

Rudakov, VM ;

Savchenko, VI ;

Sheverdenkin, EV ;

Sheverdenkina, OG ;

Zheltyakov, AY .

THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2002, 36 (05) :472-476

[5] Dependence of the kinetics of gas phase methane oxidation at high pressures on the concentration of oxygen and on temperature [J].

Arutyunov, VS ;

Basevich, VY ;

Vedeneev, VI ;

Parfenov, YV ;

Sokolov, OV .

RUSSIAN CHEMICAL BULLETIN, 1996, 45 (01) :45-48

[6]

Belyaev A.A., 2018, GORENIE VZRYV, V11, P19, DOI [10.30826/CE18110102, DOI 10.30826/CE18110102]

[7] The slow oxidation of methane at low temperatures. [J].

Bone, WA ;

Wheeler, RV .

JOURNAL OF THE CHEMICAL SOCIETY, 1902, 81 :535-549

[8]

Boomer E.H., 1937, Can. J. Res, V15, P414, DOI 10.1139/cjr37b-046

[9] Efficient methanol synthesis: Perspectives, technologies and optimization strategies [J].

Bozzano, Giulia ;

Manenti, Flavio .

PROGRESS IN ENERGY AND COMBUSTION SCIENCE, 2016, 56 :71-105

[10]

Brockhaus R, 1981, PROCESS MANUFACTURE

← 1 2 3 4 5 6 7 →