Anionic polymerization of ethyl acrylate initiated by tetrabutylammonium azide: direct synthesis of end-clickable polyacrylate

被引：5

作者：

Kataoka, Yuki ^{[1
]}

Kohsaka, Yasuhiro ^{[2
]}

Kitaura, Takehiro ^{[1
]}

Domae, Shogo ^{[1
]}

Ishihara, Shoya ^{[1
]}

Kitayama, Tatsuki ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Machikaneyama 1-3, Toyonaka, Osaka 5608531, Japan

[2] Shinshu Univ, Fac Text Sci & Technol, 3-15-1 Tokida, Ueda, Nagano 3868567, Japan

来源：

POLYMER CHEMISTRY | 2017年 / 8卷 / 26期

关键词：

TRANSFER RADICAL POLYMERIZATION; ONE-POT SYNTHESIS; BLOCK-COPOLYMERS; STAR POLYMERS; CHEMISTRY; FUNCTIONALIZATION; METHACRYLATE; CONJUGATION;

D O I：

10.1039/c7py00560a

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Tetrabutylammonium azide was found to initiate the anionic polymerization of ethyl acrylate (EA) in the presence of alkyl-aluminum bisphenoxides in toluene to afford azide-end polymers with narrow molecular weight distributions in quantitative yields. The resulting polymers showed high enough reactivity for the copper-catalyzed azide-alkyne cycloaddition.

引用

页码：3858 / 3861

页数：4

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