Co@NH2-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H2 production

被引：349
|
作者：
Nasalevich, M. A. [1 ]
Becker, R. [2 ]
Ramos-Fernandez, E. V. [3 ]
Castellanos, S. [1 ]
Veber, S. L. [4 ]
Fedin, M. V. [4 ]
Kapteijn, F. [1 ]
Reek, J. N. H. [2 ]
van der Vlugt, J. I. [2 ]
Gascon, J. [1 ]
机构：
[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands
[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands
[3] Univ Alicante, Inst Univ Mat, Dept Quim Inorgan, Lab Mat Avanzados, E-03080 Alicante, Spain
[4] Int Tomog Ctr, Lab Magnet Resonance, Novosibirsk 630090, Russia
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 01期
关键词：
ELECTRON-PARAMAGNETIC-RES; EFFICIENT HYDROGEN-PRODUCTION; CHARGE SEPARATION; WATER OXIDATION; CARBON-DIOXIDE; REDUCTION; PHOTOCATALYSIS; EVOLUTION; COBALT; CATALYST;
D O I：
10.1039/c4ee02853h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.
引用
收藏
页码：364 / 375
页数：12
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