Co@NH2-MIL-125(Ti): cobaloxime-derived metal-organic framework-based composite for light-driven H2 production

被引：353

作者：

Nasalevich, M. A. ^{[1
]}

Becker, R. ^{[2
]}

Ramos-Fernandez, E. V. ^{[3
]}

Castellanos, S. ^{[1
]}

Veber, S. L. ^{[4
]}

Fedin, M. V. ^{[4
]}

Kapteijn, F. ^{[1
]}

Reek, J. N. H. ^{[2
]}

van der Vlugt, J. I. ^{[2
]}

Gascon, J. ^{[1
]}

机构：

[1] Delft Univ Technol, NL-2628 BL Delft, Netherlands

[2] Univ Amsterdam, Vant Hoff Inst Mol Sci, NL-1098 XH Amsterdam, Netherlands

[3] Univ Alicante, Inst Univ Mat, Dept Quim Inorgan, Lab Mat Avanzados, E-03080 Alicante, Spain

[4] Int Tomog Ctr, Lab Magnet Resonance, Novosibirsk 630090, Russia

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2015年 / 8卷 / 01期

关键词：

ELECTRON-PARAMAGNETIC-RES; EFFICIENT HYDROGEN-PRODUCTION; CHARGE SEPARATION; WATER OXIDATION; CARBON-DIOXIDE; REDUCTION; PHOTOCATALYSIS; EVOLUTION; COBALT; CATALYST;

D O I：

10.1039/c4ee02853h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present a synthetic strategy for the efficient encapsulation of a derivative of a well-defined cobaloxime proton reduction catalyst within a photoresponsive metal-organic framework (NH2-MIL-125(Ti)). The resulting hybrid system Co@MOF is demonstrated to be a robust heterogeneous composite material. Furthermore, Co@MOF is an efficient and fully recyclable noble metal-free catalyst system for light-driven hydrogen evolution from water under visible light illumination.

引用

收藏

页码：364 / 375

页数：12

相关论文

共 60 条

[1] Semiconductor behavior of a metal-organic framework (MOF) [J].

Alvaro, Mercedes ;

Carbonell, Esther ;

Ferrer, Belen ;

Llabres i Xamena, Francesc X. ;

Garcia, Hermenegildo .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (18) :5106-5112

[2] Splitting Water with Cobalt [J].

Artero, Vincent ;

Chavarot-Kerlidou, Murielle ;

Fontecave, Marc .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (32) :7238-7266

[3] New Insights into the Mechanism of Visible Light Photocatalysis [J].

Banerjee, Swagata ;

Pillai, Suresh C. ;

Falaras, Polycarpos ;

O'Shea, Kevin E. ;

Byrne, John A. ;

Dionysiou, Dionysios D. .

JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2014, 5 (15) :2543-2554

[4] Self-templated synthesis of nanoporous CdS nanostructures for highly efficient photocatalytic hydrogen production under visible [J].

Bao, Ningzhong ;

Shen, Liming ;

Takata, Tsuyoshi ;

Domen, Kazunari .

CHEMISTRY OF MATERIALS, 2008, 20 (01) :110-117

[5] THE ELECTRON-PARAMAGNETIC-RES OF THE INHIBITOR DERIVATIVES OF COBALT CARBONIC-ANHYDRASE [J].

BENCINI, A ;

BERTINI, I ;

CANTI, G ;

GATTESCHI, D ;

LUCHINAT, C .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1981, 14 (01) :81-93

[6] Hydrogen evolution by cobalt tetraimine catalysts adsorbed on electrode surfaces [J].

Berben, Louise A. ;

Peters, Jonas C. .

CHEMICAL COMMUNICATIONS, 2010, 46 (03) :398-400

[7] A Computational Study of the Mechanism of Hydrogen Evolution by Cobalt(Diimine-Dioxime) Catalysts [J].

Bhattacharjee, Anirban ;

Andreiadis, Eugen S. ;

Chavarot-Kerlidou, Murielle ;

Fontecave, Marc ;

Field, Martin J. ;

Artero, Vincent .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (45) :15166-15174

[8] Electronic and vibrational properties of a MOF-5 metal-organic framework: ZnO quantum dot behaviour [J].

Bordiga, S ;

Lamberti, C ;

Ricchiardi, G ;

Regli, L ;

Bonino, F ;

Damin, A ;

Lillerud, KP ;

Bjorgen, M ;

Zecchina, A .

CHEMICAL COMMUNICATIONS, 2004, (20) :2300-2301

[9] Electronic Chemical Potentials of Porous Metal-Organic Frameworks [J].

Butler, Keith T. ;

Hendon, Christopher H. ;

Walsh, Aron .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (07) :2703-2706

[10]

Costa G., 1969, Inorg. Chim. Acta, V3, P323

← 1 2 3 4 5 6 →