Thermal degradation and combustion of a polypropylene nanocomposite based on organically modified layered aluminosilicate

被引:14
作者
Lomakin, S. M.
Dubnikova, I. L.
Berezina, S. M.
Zaikov, G. E.
机构
[1] Russian Acad Sci, Emanuel Inst Biochem Phys, Moscow 119991, Russia
[2] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/S0965545X06010111
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The specific features of thermal degradation and combustion of polypropylene nanocomposites based on organically modified layered aluminosilicate were studied. On the basis of thermogravimetric analysis data, a kinetic model that takes into account the diffusive character of the thermal degradation process for the PP nanocomposite was proposed. The basic flammability parameters of the nanocomposite were determined with the use of a cone calorimeter. The influence of diffusion constraints in the charred nanocomposite layer on the maximum heat release rate as a principal parameter of flammability was considered.
引用
收藏
页码:72 / 84
页数:13
相关论文
共 30 条
[1]   HEAT RELEASE RATE - THE SINGLE MOST IMPORTANT VARIABLE IN FIRE HAZARD [J].
BABRAUSKAS, V ;
PEACOCK, RD .
FIRE SAFETY JOURNAL, 1992, 18 (03) :255-272
[2]  
Babrauskas V., 1995, Fire Mater, V19, P243, DOI [10.1002/fam.810190602, DOI 10.1002/FAM.810190602]
[3]   Classification of volatile products from the temperature-programmed pyrolysis of polypropylene (PP), atactic-polypropylene (APP) and thermogravimetrically derived kinetics of pyrolysis [J].
Ballice, L ;
Reimert, R .
CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2002, 41 (04) :289-296
[4]   Kinetic study on the thermal degradation of polypropylene and polyethylene [J].
Bockhorn, H ;
Hornung, A ;
Hornung, U ;
Schwaller, D .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 48 (02) :93-109
[5]   The thermal degradation kinetics of polypropylene .3. Thermogravimetric analyses [J].
Chan, JH ;
Balke, ST .
POLYMER DEGRADATION AND STABILITY, 1997, 57 (02) :135-149
[6]   Processing degradation of polyamide 6/montmorillonite clay nanocomposites and clay organic modifier [J].
Davis, RD ;
Gilman, JW ;
VanderHart, DL .
POLYMER DEGRADATION AND STABILITY, 2003, 79 (01) :111-121
[7]  
FRIEDMAN HL, 1965, J POLYM SCI C, V6, P175
[8]   A kinetic study of thermal degradation of polypropylene [J].
Gao, ZM ;
Kaneko, T ;
Amasaki, I ;
Nakada, M .
POLYMER DEGRADATION AND STABILITY, 2003, 80 (02) :269-274
[9]   Polymer layered silicate nanocomposites [J].
Giannelis, EP .
ADVANCED MATERIALS, 1996, 8 (01) :29-&
[10]  
Gilman JW, 1999, CHEMISTRY AND TECHNOLOGY OF POLYMER ADDITIVES, P249