Synthesis of a Novel Mono-(6-N-allylamino-6-deoxy)-β-cyclodextrin Functional Monomer

被引：0
作者：
Chen, Guolin [1 ]
Tang, Ling [1 ]
Feng, Feng [1 ]
Liu, Zhimin [1 ]
Liao, Min [1 ]
Xu, Zhigang [1 ]
Liu, Yujian [1 ]
机构：
[1] Kunming Univ Sci & Technol, Fac Sci, Dept Chem, Kunming, Peoples R China
来源：
PROCEEDINGS OF THE 2014 INTERNATIONAL CONFERENCE ON MECHATRONICS, ELECTRONIC, INDUSTRIAL AND CONTROL ENGINEERING | 2014年 / 5卷
关键词：
mono-(6-N-allylamino-6-deoxy)-beta-cyclodextrin; mono-(6-p-toluenesulfonyl)-beta-cyclodextrin; beta-Cyclodextrin; allylamine; functional monomer; CHIRAL STATIONARY-PHASE; CYCLOMALTOHEPTAOSE BETA-CYCLODEXTRIN; SILICA-GEL; CHROMATOGRAPHIC PROPERTIES; IMPRINTED POLYMERS; ENANTIOSEPARATION; RECOGNITION; PERFORMANCE; DERIVATIVES;
D O I：
暂无
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
beta-cyclodextrin (beta-CD) is a kind of cyclic oligosaccharide with a unit of D-glucopyranose. It shows good molecular recognition ability for its unique physical and chemical properties and suitable cavity structure. It also is an important supermolecule. It is easy to be derived to get a variety of functional monomers which could be used for chromatographic solid phases and molecularly imprinted polymers. A novel mono-(6-N-allylamino-6-deoxy)-beta-CD was synthesized by using mono-(6-p-toluenesulfonyl)-beta-cyclodextrin (6-OTs-beta-CD) and allylamine as reactants in the solvent of allylamine. The reaction conditions, such as reaction temperature, molar ratio of reactants and reaction time, were optimized. And the yield of 83.9% could be obtained based on the optimized conditions. The product was characterized by FT-IR, MS and 1HNMR. The characterization results further confirmed that the target product of mono-(6-N-allylamino-6-deoxy)-beta-CD was successfully synthesized. The product was a novel functional monomer. It could be used for the preparation of polymers for further adsorption study.
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页码：1079 / 1082
页数：4
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