Synthesis of a Novel Mono-(6-N-allylamino-6-deoxy)-β-cyclodextrin Functional Monomer

被引：0

作者：

Chen, Guolin ^{[1
]}

Tang, Ling ^{[1
]}

Feng, Feng ^{[1
]}

Liu, Zhimin ^{[1
]}

Liao, Min ^{[1
]}

Xu, Zhigang ^{[1
]}

Liu, Yujian ^{[1
]}

机构：

[1] Kunming Univ Sci & Technol, Fac Sci, Dept Chem, Kunming, Peoples R China

来源：

PROCEEDINGS OF THE 2014 INTERNATIONAL CONFERENCE ON MECHATRONICS, ELECTRONIC, INDUSTRIAL AND CONTROL ENGINEERING | 2014年 / 5卷

关键词：

mono-(6-N-allylamino-6-deoxy)-beta-cyclodextrin; mono-(6-p-toluenesulfonyl)-beta-cyclodextrin; beta-Cyclodextrin; allylamine; functional monomer; CHIRAL STATIONARY-PHASE; CYCLOMALTOHEPTAOSE BETA-CYCLODEXTRIN; SILICA-GEL; CHROMATOGRAPHIC PROPERTIES; IMPRINTED POLYMERS; ENANTIOSEPARATION; RECOGNITION; PERFORMANCE; DERIVATIVES;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

beta-cyclodextrin (beta-CD) is a kind of cyclic oligosaccharide with a unit of D-glucopyranose. It shows good molecular recognition ability for its unique physical and chemical properties and suitable cavity structure. It also is an important supermolecule. It is easy to be derived to get a variety of functional monomers which could be used for chromatographic solid phases and molecularly imprinted polymers. A novel mono-(6-N-allylamino-6-deoxy)-beta-CD was synthesized by using mono-(6-p-toluenesulfonyl)-beta-cyclodextrin (6-OTs-beta-CD) and allylamine as reactants in the solvent of allylamine. The reaction conditions, such as reaction temperature, molar ratio of reactants and reaction time, were optimized. And the yield of 83.9% could be obtained based on the optimized conditions. The product was characterized by FT-IR, MS and 1HNMR. The characterization results further confirmed that the target product of mono-(6-N-allylamino-6-deoxy)-beta-CD was successfully synthesized. The product was a novel functional monomer. It could be used for the preparation of polymers for further adsorption study.

引用

页码：1079 / 1082

页数：4

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