Modeling of the molybdenum center in the nitrogenase FeMo-cofactor

被引：73

作者：

Barrière, F ^{[1
]}

机构：

[1] Natl Univ Ireland Univ Coll Galway, Dept Chem, Galway, Ireland

来源：

COORDINATION CHEMISTRY REVIEWS | 2003年 / 236卷 / 1-2期

关键词：

nitrogenase; FeMo-cofactor; molybdenum; sulfur; nitrogen fixation; modeling;

D O I：

10.1016/S0010-8545(02)00183-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The functional, structural and theoretical chemical approaches to specifically model the molybdenum center of the nitrogenase enzyme are reviewed. We show how dinitrogen can be reduced at monometallic centers and highlight attempts to develop a nitrogenase-relevant dinitrogen reduction chemistry at molybdenum-sulfur complexes and clusters. The theoretical work addressing the molybdenum issue is also reported together with models for nitrogenase function, some of them directly involving the molybdenum atom. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：71 / 89

页数：19

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