Modeling of the molybdenum center in the nitrogenase FeMo-cofactor

被引：73
作者：
Barrière, F [1 ]
机构：
[1] Natl Univ Ireland Univ Coll Galway, Dept Chem, Galway, Ireland
来源：
COORDINATION CHEMISTRY REVIEWS | 2003年 / 236卷 / 1-2期
关键词：
nitrogenase; FeMo-cofactor; molybdenum; sulfur; nitrogen fixation; modeling;
D O I：
10.1016/S0010-8545(02)00183-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The functional, structural and theoretical chemical approaches to specifically model the molybdenum center of the nitrogenase enzyme are reviewed. We show how dinitrogen can be reduced at monometallic centers and highlight attempts to develop a nitrogenase-relevant dinitrogen reduction chemistry at molybdenum-sulfur complexes and clusters. The theoretical work addressing the molybdenum issue is also reported together with models for nitrogenase function, some of them directly involving the molybdenum atom. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：71 / 89
页数：19
相关论文
共 184 条
  • [1] ABUBAKAR M, 1988, J CHEM SOC DALTON, P2545
  • [2] CONVERSION OF A MOLYBDENUM NITRIDE TO THE AMIDE AND THENCE TO AN OXIDE AND AMMONIA, REACTIONS INVOLVING FORMAL 1,3-PROTOTROPIC SHIFTS - X-RAY STRUCTURES OF TRANS-[MO(NH2)(OH)(DPPE)(2)][OTF](2) AND TRANS-[MOO(OME)(DPPE)(2)][BPH(4)] (DPPE=PH(2)PCH(2)CH(2)PPH(2) OTF=CF3SO3)
    ADACHI, T
    HUGHES, DL
    IBRAHIM, SK
    OKAMOTO, S
    PICKETT, CJ
    YABANOUCHI, N
    YOSHIDA, T
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (10) : 1081 - 1083
  • [3] ADAMS C, 1999, CHEM IND, V19, P740
  • [4] In pursuit of the molybdenum(III) tris(thiolate) fragment:: Unusual structure of a dimolybdenum μ-nitrido complex
    Agapie, T
    Odom, AL
    Cummins, CC
    [J]. INORGANIC CHEMISTRY, 2000, 39 (02) : 174 - 179
  • [5] [Anonymous], MOLYBDENUM ENZYMES
  • [6] Baker PK, 1998, CHEM SOC REV, V27, P125
  • [7] PROTONATION OF BIS[1,2-BIS(DIETHYLPHOSPHINO)ETHANE]BIS(DINITROGEN)-MOLYBDENUM AND BIS[1,2-BIS(DIETHYLPHOSPHINO)ETHANE]BIS(DINITROGEN)-TUNGSTEN WITH FLUOROBORIC ACID-DIETHYL ETHER (1/1) IN BENZENE - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS[1,2-BIS(DIETHYLPHOSPHINO)ETHANE]FLUORO[HYDRAZIDO(2-)]TUNGSTEN TETRAFLUOROBORATE
    BARCLAY, JE
    HILLS, A
    HUGHES, DL
    LEIGH, GJ
    MACDONALD, CJ
    ABUBAKAR, M
    MOHDALI, H
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (08): : 2503 - 2507
  • [8] Electrochemical deprotection of a substrate binding site in [Mo-2(cp)(2)(mu-SMe)(3)(mu-Cl)] (cp=eta(5)-C5H5) via chloride-bridge opening. Kinetics of MeCN and Bu(t)NC binding at this site
    Barriere, F
    LeMest, Y
    Petillon, FY
    PoderGuillou, S
    Schollhammer, P
    Talarmin, J
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (20): : 3967 - 3976
  • [9] Exo-iron centres linked to MoFeS clusters
    Barrière, F
    Evans, DJ
    Hughes, DL
    Ibrahim, SK
    Talarmin, J
    Pickett, CJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (06): : 957 - 964
  • [10] Extended Huckel calculations on functional and structural models of the FeMo-cofactor of nitrogenase
    Barrière, F
    Pickett, CJ
    Talarmin, J
    [J]. POLYHEDRON, 2001, 20 (1-2) : 27 - 36
12345678910