A boot-strap Poisson-Boltzmann theory for the structure and thermodynamics of charged colloidal solutions

被引：13

作者：

Petris, SN ^{[1
]}

Chan, DYC

Linse, P

机构：

[1] Univ Melbourne, Dept Math & Stat, Particulate Fluids Proc Ctr, Melbourne, Vic 3010, Australia

[2] Lund Univ, Ctr Chem & Chem Engn, S-22100 Lund, Sweden

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 118卷 / 11期

关键词：

D O I：

10.1063/1.1541610

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structural properties and thermodynamics of one- and two-component solutions of charged colloidal particles with explicit counterions have been investigated by Monte Carlo simulation. A boot-strap Poisson-Boltzmann (BSPB) theory has been developed to interpret these results and the accuracy of its predictions is compared with other existing theories. The BSPB was also used to predict the gas-liquid binodal and spinodal curves for a one-component system with colloid charge to counterion-charge ratio Z(r)=10. (C) 2003 American Institute of Physics.

引用

页码：5248 / 5259

页数：12

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