Coexistence of conducting and magnetic electrons based on molecular π-electrons in the supramolecular conductor (Me-3,5-DIP)[Ni(dmit)2]2

被引：67

作者：

Kosaka, Yosuke

Yamamoto, Hiroshi M.

Nakao, Akiko

Tamura, Masafumi

Kato, Reizo ^{[1
]}

机构：

[1] Saitama Univ, Fac Sci, Dept Chem, Urawa, Saitama 3388570, Japan

[2] JST, CREST, RIKEN, Wako, Saitama 3510198, Japan

[3] High Energy Accelerator Res Org, Tsukuba, Ibaraki 3050801, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 11期

关键词：

ORGANIC METAL; SALTS; SUPERCONDUCTIVITY; FERROMAGNETISM;

D O I：

10.1021/ja0687825

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The supramolecular conductor (Me-3,5-DIP)[Ni(dmit)(2)](2), which was prepared by electrochemical oxidation, consists of two crystallographically independent layers of Ni(dmit)(2) anions (Layers I and II). The tight-binding band calculation suggests that Layer I is in a Mott insulating state to include localized spins, and Layer II displays two-dimensional metallic conduction. The coexistence of the two contrastive molecular pi-electrons of Ni(dmit)(2) anions is evidenced by electrical resistivity and magnetic susceptibility measurements.

引用

页码：3054 / +

页数：3

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