Two Isostructural Coordination Polymers Showing Diverse Magnetic Behaviors: Weak Coupling (NiII) and an Ordered Array of Single-Chain Magnets (CoII)

被引：30

作者：

Chen, Min ^{[1
]}

Zhao, Hui ^{[1
]}

Carolina Sanudo, E. ^{[2
,3
]}

Liu, Chun-Sen ^{[1
]}

Du, Miao ^{[1
,4
]}

机构：

[1] Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China

[2] Univ Barcelona, Dept Quim Inorgan, Diagonal 645, Barcelona 08028, Spain

[3] Univ Barcelona, Inst Nanociencia & Nanotecnol, Diagonal 645, E-08028 Barcelona, Spain

[4] Tianjin Normal Univ, Tianjin Key Lab Struct & Performance Funct Mol, MOE Key Lab Inorgan Organ Hybrid Funct Mat Chem, Coll Chem, Tianjin 300387, Peoples R China

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 08期

基金：

中国国家自然科学基金;

关键词：

MOLECULE MAGNET; COMPLEXES; ANISOTROPY; LIGANDS; NETWORKS;

D O I：

10.1021/acs.inorgchem.5b02716

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two isomorphic 3-D complexes with the formulas [M-3(TPTA) (OH)(2)(H2O)(4)](n) (M = Ni for 1 and Co for 2; H(4)TPTA = [1,1':4',1 ''-terphenyl]-2',3,3 '',5'-tetracarboxylic acid) have been synthesized and magnetically characterized. Complexes 1 (Ni-II) and 2 (Con) have the same 1-D rod-shaped inorganic SBUs but exhibit significantly different magnetic properties. Complex 2(Co-II) is a 3-D arrangement of a 1-D Co-II single-chain magnet (SCM), while complex 1(Ni-II) exhibits weak coupling.

引用

页码：3715 / 3717

页数：3

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