Comparative impedance spectroscopy study of rutile and anatase TiO2 film electrodes

被引：49

作者：

Dolata, M ^{[1
]}

Kedzierzawski, P ^{[1
]}

Augustynski, J ^{[1
]}

机构：

[1] UNIV GENEVA,DEPT CHEM MINERALE ANALYT & APPL,CH-1211 GENEVA,SWITZERLAND

来源：

ELECTROCHIMICA ACTA | 1996年 / 41卷 / 7-8期

关键词：

titanium dioxide; rutile; anatase; impedance; semiconducting films;

D O I：

10.1016/0013-4686(95)00449-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The purpose of this work was a comparative electrochemical impedance analysis of the titanium dioxide-solution interface for two kinds of thin film samples consisting respectively of anatase and rutile. These kind of films, frequently used in photoelectrochemical experiments, have recently been the subject of detailed physical studies showing important differences in electrical properties between those two forms of TiO2. The EIS measurements were carried out over a wide frequency range (from 0.03 Hz to 10kHz), analysing the whole spectrum.

引用

页码：1287 / 1293

页数：7

共 24 条

[1] PHOTOCATALYTIC DEGRADATION OF PHENOL IN AQUEOUS TITANIUM-DIOXIDE DISPERSIONS [J].

AUGUGLIARO, V ;

PALMISANO, L ;

SCLAFANI, A ;

MINERO, C ;

PELIZZETTI, E .

TOXICOLOGICAL AND ENVIRONMENTAL CHEMISTRY, 1988, 16 (02) :89-109

[2] THE ROLE OF THE SURFACE INTERMEDIATES IN THE PHOTOELECTROCHEMICAL BEHAVIOR OF ANATASE AND RUTILE TIO2 [J].

AUGUSTYNSKI, J .

ELECTROCHIMICA ACTA, 1993, 38 (01) :43-46

[3] NOVEL SEMICONDUCTING ELECTRODES FOR PHOTOSENSITIZED ELECTROLYSIS OF WATER [J].

AUGUSTYNSKI, J ;

HINDEN, J ;

STALDER, C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1977, 124 (07) :1063-1064

[4]

De Levie R, 1967, ADV ELECTROCHEMISTRY, V6, P329

[5] THE ELECTRONIC-PROPERTIES OF DISORDERED PASSIVE FILMS [J].

DEAN, MH ;

STIMMING, U .

CORROSION SCIENCE, 1989, 29 (2-3) :199-211

[6] INVESTIGATION ON FREQUENCY-DEPENDENCE OF IMPEDANCE OF NEARLY IDEALLY POLARIZABLE SEMICONDUCTOR ELECTRODES CDSE, CDS AND TIO2 [J].

DUTOIT, EC ;

VANMEIRHAEGHE, RL ;

CARDON, F ;

GOMES, WP .

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1975, 79 (12) :1206-1213

[7]

FINKLEA HO, 1988, SEMICONDUCTOR ELECTR, V55, P71

[8] PRODUCTION AND TESTING METHODS OF DIFFERENT TIO2 PHOTOANODES [J].

HARTIG, KJ ;

GETOFF, N .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 1986, 11 (12) :773-781

[9] CHARACTERIZATION OF SOME TERNARY III-V SEMICONDUCTOR ELECTROLYTE INTERFACES UTILIZING ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY [J].

KOCHA, SS ;

LIEBERT, BE .

ELECTROCHIMICA ACTA, 1993, 38 (14) :1993-1997

[10] CORRELATION BETWEEN THE SURFACE-COMPOSITION OF PT/TIO2 CATALYSTS AND THEIR ADSORPTION BEHAVIOR IN AQUEOUS-SOLUTIONS [J].

KOUDELKA, M ;

MONNIER, A ;

SANCHEZ, J ;

AUGUSTYNSKI, J .

JOURNAL OF MOLECULAR CATALYSIS, 1984, 25 (1-3) :295-305

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