Efficient and convenient oxidation of sulfides to sulfoxides with molecular oxygen catalyzed by Mn(OAc)2 in ionic liquid [C12mim][NO3]

被引：15
作者：
Hu, Yu-Lin [1 ]
Fang, Dong [1 ]
Xing, Rong [1 ]
机构：
[1] Yancheng Teachers Univ, Coll Chem & Chem Engn, Yancheng 224002, Peoples R China
来源：
RSC ADVANCES | 2014年 / 4卷 / 93期
关键词：
SELECTIVE AEROBIC OXIDATION; ASYMMETRIC OXIDATION; THIOETHER-OXIDATION; HYDROGEN-PEROXIDE; ACID; COMPLEX; MILD; TEMPERATURE; SULFONES; H2O2;
D O I：
10.1039/c4ra06695b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple, efficient, and eco-friendly procedure for aerobic oxidation of sulfides catalyzed by Mn(OAc)(2)/[C(12)mim][NO3] has been developed. The reactions afford the target products in good to high yields and no over-oxidation was observed. The products can be easily separated, and the catalytic system can be recycled without loss of catalytic activity.
引用
收藏
页码：51140 / 51145
页数：6
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