Carbon-carbon coupling reactions on triruthenium clusters:: synthesis and structure of Ru3(CO)9[μ3-η3-PhCCCC(H)Ph][μ2-NS(O)MePh] and Ru3(μ2-CO)(CO)7[μ3-η3-PhCCCC(H)Ph][μ3-NS(O)MePh]

被引：18
|
作者：
Ferrand, V
Gambs, C
Derrien, N
Bolm, C
Stoeckli-Evans, H
Suss-Fink, G
机构：
[1] Univ Neuchatel, Inst Chim, CH-2000 Neuchatel, Switzerland
[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52058 Aachen, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 549卷 / 1-2期
关键词：
clusters; ruthenium; alkynes; carbon-carbon coupling; crystal structures;
D O I：
10.1016/S0022-328X(97)00507-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of the electron-deficient cluster (mu(2)-H)Ru-3(CO)(9)[mu(3)-NS(O)MePh] (1) with para-nitrotolane gives, with coupling of two alkyne units and elimination of the para-nitrophenyl fragment, the trinuclear complexes Ru-3(CO)(9)[mu(3)-eta(3)-PhCCCC(H)Ph][mu(2)-NS(O)MePh] (2) and Ru-3(mu(2)-CO)(CO)(7)[mu(3)-eta(3)-PhCCCC(H)Ph][mu(3)-NS(O)MePh] (3). The resulting organic moiety, coordinated as mu(3)-eta(3)-5e-donor, is best considered as a butenynyl (PhC=C-C=C(H)Ph) ligand in 2 and as a butatrienyl (PhC=C=C=C(H)Ph) ligand in 3. From the reaction mixture, the two isomeric vinyl complexes Ru-3(mu(2)-CO)(2)(CO)(6)[mu(2)-eta(2)-PhC=C(H)(C6H4-p-NO2)][mu(3)-NS(O)MePh] (4a) and Ru-3(mu(2)-CO)(2)(CO)(6)[mu(2)-eta(2)-(C6H4-P-NO2)-C=C(H)Ph]-[mu(3)-NS(O)MePh] (4b) complexes can also be isolated. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：275 / 282
页数：8
相关论文
共 50 条
  • [21] Two gold-ruthenium clusters derived from RU3(μ-H)3(μ3-CBr)(CO)9
    Bruce, MI
    Humphrey, PA
    Skelton, BW
    White, AH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (15) : 2558 - 2561
  • [22] A re-examination of the reaction between 1,1′-bis(diphenylphosphino)ferrocene (dppf) diselenide and [Ru3(CO)12]. Electrochemical behaviour of the isomeric Nido-clusters [Ru3(μ3-Se)2(dppf)(CO)7] and [Ru3(μ3-Se)2(μ-dppf)(CO)7] and crystal structure of [Ru3Se{μ-P(Ph)C5H4FeC5H4PPh2}(μ-OCPh)(CO)6]
    de Biani, FF
    Graiff, C
    Opromolla, G
    Predieri, G
    Tiripicchio, A
    Zanello, P
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 637 : 586 - 594
  • [23] Chalcogenide-capped triruthenium clusters: X-ray structures of [Ru3(CO)6(μ3-CO){P(C4H3S)3}(μ-dppm)(μ3-O)] and [(μ-H)2Ru3(CO)6{P(C4H3S)3}(μ-dppm)(μ3-S)]
    Sikder, Md. Delwar H.
    Ghosh, Shishir
    Kabir, Shariff E.
    Hogarth, Graeme
    Tocher, Derek A.
    INORGANICA CHIMICA ACTA, 2011, 376 (01) : 170 - 174
  • [24] Activation of carbon disulfide on triruthenium clusters:: Synthesis and X-ray crystal structure analysis of [RU3(CO)5(μ-H)2(μ-PCy2)(μ-Ph2PCH2PPh2){μ-η2-PCy2C(S)}(μ3-S)] and [Ru3(CO)5(CS)(μ-H)(μ-PtBu2)(μ-PCy2)2(μ3-S)]
    Böttcher, HC
    Graf, M
    Merzweiler, K
    Wagner, C
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (12): : 2657 - 2662
  • [25] Reactions of 1,4-diphenylbut-1-en-3-yne and 1,4-diferrocenylbuta-1,3-diyne with Ru3(CO)10(μ-dppm).: Unusual structures of the clusters Ru3(CO)5(μ-CO)(μ-dppm){μ3-C4Ph2(CH=CHPh)2} (two isomers) and Ru3(CO)5(μ-CO)(μ-dppm)(μ3-C4Fc2(C≡CFc)2}
    Koridze, AA
    Zdanovich, VI
    Lagunova, VY
    Petukhova, II
    Dolgushin, FM
    RUSSIAN CHEMICAL BULLETIN, 2000, 49 (07) : 1321 - 1322
  • [26] Reactions of 1,4-diphenylbut-1-en-3-yne and 1,4-diferrocenylbuta-1,3-diyne with Ru3(CO)10(μ-dppm). Unusual structures of the clusters Ru3(CO)5(η-CO)(η-dppm){μ3-C4Ph2(CH=CHPh)2} (two isomers) and Ru3(CO)5(η-CO)(η-dppm){μ3-C4Fc2(CH≡CFc)2}
    A. A. Koridze
    V. I. Zdanovich
    V. Yu. Lagunova
    I. I. Petukhova
    F. M. Doglushin
    Russian Chemical Bulletin, 2000, 49 : 1321 - 1322
  • [27] Mixed main group transition metal clusters: Reactions of [Ru3(CO)10(μ-dppm)] with Ph3SnH
    Khan, Md. Mehedi M.
    Ghosh, Shishir
    Hogarth, Graeme
    Tocher, Derek A.
    Richmond, Michael G.
    Kabir, Shariff E.
    Roesky, Herbert W.
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2017, 840 : 47 - 55
  • [28] Activation of carbon disulfide on triruthenium clusters:: Synthesis and X-ray crystal structure analysis of [Ru3(CO)4(μ-PCy2)2(μ-Ph2PCH2PPh2)(μ3-S){μ3-η2-CSC(S)S}]
    Böttcher, HC
    Fernandez, M
    Graf, M
    Merzweiler, K
    Wagner, C
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2002, 628 (11): : 2247 - 2248
  • [29] Ring-opening reactions of thiomorpholine and thiazolidine by [Ru3(CO)12]:: crystal structures of [Ru3(μ-H)(μ-η2-SCH2CH2NH2)(CO)9] and [Ru2(μ-η3-SCH2CH2NHCH2)(CO)6]
    Hanif, KM
    Hursthouse, MB
    Kabir, SE
    Malik, KMA
    Rosenberg, E
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1999, 580 (01) : 60 - 65
  • [30] Multiple oxidative addition of diphenyl-2-thienylphosphine selenide to [Ru3(CO)12]:: crystal and molecular structure of [Ru3(μ3-Se)(μ-PPh2)(μ-η1:η2-C4H3S)(CO)6{P(C4H3S)Ph2}]
    Cauzzi, D
    Graiff, C
    Massera, C
    Predieri, G
    Tiripicchio, A
    INORGANICA CHIMICA ACTA, 2000, 300 : 471 - 476
12345