Removal of toxic metals from wastewater by Brazilian natural scolecite

The cation-exchange capacity of Brazilian natural zeolite, identified as scolecitc, was studied with the aim of evaluating its applications in wastewater control. We investigated the process of sorption of chromium(Ill), nickel(II), cadmium(II), and manganese(II) in synthetic aqueous effluents, including sorption isotherms of single-metal solutions at 298, 313, and 333 K, by batch experiments, and the influence of pH on the process. The results have demonstrated that removal of metals from specific metal solutions is best described by a Freundlich isotherm, in which the values obtained for the K-f constants were in the following order: Cr > Mn > Cd > Ni. A Lagergren pseudo-second-order was the model that best described the sorption mechanism. The retention of metals was shown to be a function of the pH; the maximum binding capacity occurring at pH values around 6.0. Thermodynamic data indicate the spontaneity of the endothermic cation-exchange process. The values of DeltaG(O) suggest the following selectivity series at 298 K: Ni > Cr > Cd > Mn. The desorption process reaches equilibrium during the first 60 min of binding, suggesting that the mechanism involves specific sites located in the external surface of the scolecite. (C) 2004 Elsevier Inc. All rights reserved.