Enhanced Light Harvesting and Electron Lifetime of Front Side-illuminated CdSe Quantum Dot-assembled TiO2 Nanotube Arrays for Quantum Dot-sensitized Solar Cells

被引:2
作者
Jung, Sung Woo [1 ]
Lee, Soo-Yong [1 ]
Park, Min-Ah [1 ]
Kim, Jae-Hong [1 ]
Kang, Soon-Hyung [2 ]
Kim, Hyunsoo [3 ]
Choi, Chel-Jong [3 ]
Ahn, Kwang-Soon [1 ]
机构
[1] Yeungnam Univ, Sch Chem Engn, Gyongsan 712749, South Korea
[2] Chonnam Natl Univ, Dept Chem Educ, Kwangju, South Korea
[3] Chonbuk Natl Univ, Sch Semicond & Chem Engn, Jeonju 561756, South Korea
基金
新加坡国家研究基金会;
关键词
light harvesting; front side illumination; quantum dot-sensitized solar cell; electron lifetime; nanotube array; DYE; EFFICIENCY; FILMS;
D O I
10.1080/15421406.2014.933386
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CdSe quantum dots (QDs)-assembled, free-standing TiO2 nanotube arrays (TNTs) are transferred to transparent fluorine-doped tin oxides (FTOs) using a sol-gel process. The TNTs on the FTO (FTO/TNT) not only provide an efficient 1-dimensional electron pathway with few recombination centers, but also allow front side illumination through the transparent FTO, providing a significantly enhanced electron lifetime and light harvesting compared to conventional TNTs on Ti foil and TiO2 nanoparticles-based mesoporous films on the FTO. These effects help improve significantly the short circuit current and open-circuit voltage of quantum dot-sensitized solar cells (QD-SSCs).
引用
收藏
页码:144 / 153
页数:10
相关论文
共 37 条
[1]   Enhanced electron diffusion length of mesoporous TiO2 film by using Nb2O5 energy barrier for dye-sensitized solar cells [J].
Ahn, Kwang-Soon ;
Kang, Moon-Sung ;
Lee, Jae-Kwan ;
Shin, Byong-Cheol ;
Lee, Ji-Won .
APPLIED PHYSICS LETTERS, 2006, 89 (01)
[2]  
Archer M. D., 2008, NANOSTRUCTURED PHOTO, P130
[3]   Chemical bath deposition of CdS quantum dots onto mesoscopic TiO2 films for application in quantum-dot-sensitized solar cells [J].
Chang, Chi-Hsiu ;
Lee, Yuh-Lang .
APPLIED PHYSICS LETTERS, 2007, 91 (05)
[4]   Large-Scale, Noncurling, and Free-Standing Crystallized TiO2 Nanotube Arrays for Dye-Sensitized Solar Cells [J].
Chen, Qingwei ;
Xu, Dongsheng .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :6310-6314
[5]   Facile fabrication of aligned doubly open-ended TiO2 nanotubes, via a selective etching process, for use in front-illuminated dye sensitized solar cells [J].
Choi, Jongmin ;
Park, Sung-Hae ;
Kwon, Young Soo ;
Lim, Jongchul ;
Song, In Young ;
Park, Taiho .
CHEMICAL COMMUNICATIONS, 2012, 48 (70) :8748-8750
[6]   An Efficient Method To Form Heterojunction CdS/TiO2 Photoelectrodes Using Highly Ordered TiO2 Nanotube Array Films [J].
Gao, Xian-Feng ;
Sun, Wen-Tao ;
Hu, Zhu-Dong ;
Ai, Guo ;
Zhang, Yi-Ling ;
Feng, Shi ;
Li, Fei ;
Peng, Lian-Mao .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (47) :20481-20485
[7]   CdTe Quantum Dots-Sensitized TiO2 Nanotube Array Photoelectrodes [J].
Gao, Xian-Feng ;
Li, Hong-Bo ;
Sun, Wen-Tao ;
Chen, Qing ;
Tang, Fang-Qiong ;
Peng, Lian-Mao .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (18) :7531-7535
[8]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[9]   Front-side illuminated CdS/CdSe quantum dots co-sensitized solar cells based on TiO2 nanotube arrays [J].
Guan, Xiao-Fang ;
Huang, Shu-Qing ;
Zhang, Quan-Xin ;
Shen, Xi ;
Sun, Hui-Cheng ;
Li, Dong-Mei ;
Luo, Yan-Hong ;
Yu, Ri-Cheng ;
Meng, Qing-Bo .
NANOTECHNOLOGY, 2011, 22 (46)
[10]   Comparison of Dye- and Semiconductor-Sensitized Porous Nanocrystalline Liquid Junction Solar Cells [J].
Hodes, Gary .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (46) :17778-17787