A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex

被引：37

作者：

Bungabong, Maricar L.

Tan, Kien Wee

Li, Yongxin

Selvaratnam, Selvasothi V.

Dongol, Krishna G.

Leung, Pak-Hing ^{[1
]}

机构：

[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Math & Phys Sci, Singapore 637616, Singapore

[2] Inst Chem & Engn Sci, Singapore 627833, Singapore

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期

关键词：

D O I：

10.1021/ic0701561

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.

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页码：4733 / 4736

页数：4

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