A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex

被引：37
作者：
Bungabong, Maricar L.
Tan, Kien Wee
Li, Yongxin
Selvaratnam, Selvasothi V.
Dongol, Krishna G.
Leung, Pak-Hing [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Math & Phys Sci, Singapore 637616, Singapore
[2] Inst Chem & Engn Sci, Singapore 627833, Singapore
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期
关键词：
D O I：
10.1021/ic0701561
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.
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页码：4733 / 4736
页数：4
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