Thermal study and evaluation of new menthol-based ionic liquids as polymeric additives

被引：16
作者：
Andrade, Carlos Kleber Z. [2 ]
Matos, Ricardo Alexandre F. [2 ]
Oliveira, Viviane B. [1 ]
Duraes, Jussara A. [1 ]
Sales, Maria J. A. [1 ]
机构：
[1] Univ Brasilia, Lab Pesquisa Polimeros LabPol, Inst Quim, BR-70904970 Brasilia, DF, Brazil
[2] Univ Brasilia, LaQMOS, Inst Quim, BR-70904970 Brasilia, DF, Brazil
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2010年 / 99卷 / 02期
关键词：
Ionic liquids; Plasticizers; Polymer morphology; Poly(methyl methacrylate); Thermal stabilizers; METHACRYLATE); PLASTICIZERS; DERIVATIVES; SOLVENTS; PMMA;
D O I：
10.1007/s10973-009-0203-4
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Thermal properties of new ionic liquids (ILs) were investigated by thermogravimetry (TG/DTG) and differential scanning calorimetry (DSC). Chlorides, tetrafluoroborates and hexafluorophosphates of (-)mentholpyrrolidinium and (-)-mentholimidazolium cations revealed good thermal stability at air atmosphere. Morphological characteristics of poly(methyl methacrylate) (PMMA) matrices doped with 10% of these ILs were also investigated by DRX and water absorption test. Into the matrix, they exhibited a very satisfactory pattern concerning the polymer thermal stabilization. DSC results show that some of these ILs also present plasticizer features since they can lower the polymer glass transition temperature (T-g) up to 317.15 K.
引用
收藏
页码：539 / 543
页数：5
相关论文
共 15 条
  • [1] Andrade CKZ, 2005, CURR ORG CHEM, V9, P195
  • [2] New measurements of the thermal conductivity of PMMA, BK7, and Pyrex 7740 up to 450K
    Assael, M. J.
    Antoniadis, K. D.
    Wu, Jiangtao
    [J]. INTERNATIONAL JOURNAL OF THERMOPHYSICS, 2008, 29 (04) : 1257 - 1266
  • [3] Chiral ionic liquids, a renewal for the chemistry of chiral solvents?: Design, synthesis and applications for chiral recognition and asymmetric synthesis
    Baudequin, C
    Brégeon, D
    Levillain, J
    Guillen, F
    Plaquevent, JC
    Gaumont, AC
    [J]. TETRAHEDRON-ASYMMETRY, 2005, 16 (24) : 3921 - 3945
  • [4] Ionic liquids and chirality: opportunities and challenges
    Baudequin, C
    Baudoux, J
    Levillain, J
    Cahard, D
    Gaumont, AC
    Plaquevent, JC
    [J]. TETRAHEDRON-ASYMMETRY, 2003, 14 (20) : 3081 - 3093
  • [5] Thiazolinium and imidazolium chiral ionic liquids derived from natural amino acid derivatives
    Bregeon, D.
    Levillain, J.
    Guillen, F.
    Plaquevent, J. -C.
    Gaumont, A. -C.
    [J]. AMINO ACIDS, 2008, 35 (01) : 175 - 184
  • [6] Physico-chemical processes in imidazolium ionic liquids
    Dupont, Jairton
    Suarez, Paulo A. Z.
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2006, 8 (21) : 2441 - 2452
  • [7] Thermal and structural behavior of Buriti oil/poly(methyl methacrylate) and Buriti oil/polystyrene materials
    Duraes, Jussara A.
    Drummond, Adriana L.
    Pimentel, T. A. P. F.
    Murta, Maria M.
    Moreira, S. G. C.
    Sales, Maria J. A.
    [J]. JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2008, 92 (02) : 529 - 534
  • [8] A new room temperature ionic liquid 1-butyl-3-trimethylsilylimidazolium hexafluorophosphate as a solvent for extraction and preconcentration of mercury with determination by cold vapor atomic absorption spectrometry
    Li, Zaijun
    Wei, Qin
    Yuan, Rui
    Zhou, Xia
    Liu, Huizhen
    Shan, Haixia
    Song, Qijun
    [J]. TALANTA, 2007, 71 (01) : 68 - 72
  • [9] MARK HF, ENCY POLYM SCI TECHN, DOI DOI 10.1002/0471440264.PST540
  • [10] Synthesis of new chiral ionic liquids based on (-)-menthol and (-)-borneol
    Matos, Ricardo Alexandre F.
    Andrade, Carlos Kleber Z.
    [J]. TETRAHEDRON LETTERS, 2008, 49 (10) : 1652 - 1655
12