Study on the properties of sodium lauroyl lactate anionic surfactant and cationic surfactant in a mixed system

被引:25
作者
Qin, Ziyu [1 ]
Zhang, Jun [1 ]
Zhou, Yuan [1 ]
Yang, Xiuquan [1 ]
机构
[1] China Res Inst Daily Chem Ind, Taiyuan 030001, Peoples R China
关键词
Mixed system; Surface activity; Synergistic; Interaction; Thermodynamic; GEMINI SURFACTANTS; MOLECULAR-INTERACTIONS; ADSORPTION; MICELLIZATION; MIXTURES; BEHAVIOR; HYDROXYETHYL; PARAMETERS; MICELLES; TENSION;
D O I
10.1016/j.molliq.2022.118544
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The surface properties and applications of mixtures of an anionic surfactant (sodium lauroyl lactate (SLL)) and cationic surfactant (gemini quaternary ammonium salt with a hydroxyl group (GC(12))) were investigated. The results showed that SLL/GC(12) surfactant mixtures have synergistic effects, yielding higher sur -face activity and greater application performance. When the mole fraction of SLL (alpha(SLL)) was 0.4, the surface tension reached its minimum value. Furthermore, based on the calculated interaction parameters, stronger attractive interactions between the mixed SLL/GC(12) surfactant molecules could be obtained at air/solution interfaces or with mixed micelles. When the mass fraction of SLL was 50%, its wetting ability and emulsifying capacity were optimal. The foam stability exceeded 95% when the mass fractions of SLL (W-SLL) were 20%, 40%, and 50%. In addition, when the mole fraction of SLL was approximately 0.5, vesicles formed easily at a total solution concentration of 3 mM. (C) 2022 Published by Elsevier B.V.
引用
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页数:11
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